chemistry kinetics Flashcards
1
Q
what is reaction rate?
A
Reaction rate is defined as the change in concentration (or amount) of a reactant or product over time.
2
Q
What is the formula for finding the rate of a chemical reaction?
A
rate of reaction= Amount of reactant used up or products formed/ time
3
Q
What are the three methods for measuring the rate of reaction.
A
-
Measuring a decrease in mass
- For reactions that produce gases, you can measure the rate by observing the decrease in mass over time.
- As gas is released, the mass decreases. This method is straightforward but should be conducted in fume cupboard for safety. - ** Measuring the volume of mass given of gas given off**
- use a gas syringe to measure the gas volume produced over time.
- This method is accurate for reactions that generate gases. - ** Timing how long a precipitate takes to form.**
- This approach is suitable when the product of the reaction is a precipitate.
- Measure how long it takes for a mark to become obscured by the precipitate.
- For consistent comparison of reaction rates, always use the same observer and reference mark
4
Q
how do you work out the gradient on a graph?
A
Gradient = change in y/ change in x
5
Q
what are the features of the Maxwell-Boltzmann distribution graph?
A
- The curve originates at the origin, indicating that no molecules have zero kinetic energy.
- it rises sharply to a peak that represents the most common kinetic energy level among the molecules. before gradually decreasing.
- the total area under the curve is equivalent to the total number of molecules.
- the peak of the curve shows the most probable kinetic energy a single molecule can have.
- on average, the kinetic energy of all molecules is a bit higher than the peak energy.
6
Q
What happens to the Maxwell-Boltzmann graph when the temperature increases?
A
- As the temperature rises, a greater number of molecules attain the kinetic energy necessary to surpass the activation energy, leading to a reaction.
- Consequently, the distribution curve shifts to the right, indicating that more molecules have acquired sufficient kinetic energy.
- Despite the total number of molecules remaining constant, the area under both curves is unchanged, which results in a lower peak height. This is because the distribution of kinetic energies broadens at higher temperatures.