organic chem definitons Flashcards
nucleophile
a nucleophile is a chemical species that has the tendency to donate a pair of electrons to an electrophile to form a chemical bond
electrophile
is a chemical species that has the tendency to bond to nucleophiles by accepting an electron pair
hydrogenation
is the process whereby hydrogen atoms bind to the double bond of a compound facilitating its conversion to a single bond, in the presence of a catalyst. like palladium platinum nickel etc.
carbocation
is defined as an ion with a positively charged carbon atom that participates in various reactions such as substitution, addition and decomposition
key differences between Sn1 reactions and Sn2 reactions
Sn1 are a two step mechanism including the creation of a carbocation intermediate. Sn2 reactions are a one step mechanism involving the direct attack of the nucleophile on the substrate.
steps in which Sn1 reactions occur
1.formation of the carbocation: the leaving group departs, forming a carbocation intermediate.
2.nucleophilic attack: the nucleophile attacks the carbocation to form the final product
3.they are slow and depend on the carbocation step.
- examples are tertiary haloalkanes
steps involved in Sn2 reactions
- occurs in a single step where the nucleophile attacks the substrate and the leaving group departs simultaneously
- This results in a transition state where the substrate is partially bonded to both the nucleophile and the leaving group.
- example would be primary haloalkanes