organic chem definitons Flashcards

1
Q

nucleophile

A

a nucleophile is a chemical species that has the tendency to donate a pair of electrons to an electrophile to form a chemical bond

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2
Q

electrophile

A

is a chemical species that has the tendency to bond to nucleophiles by accepting an electron pair

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3
Q

hydrogenation

A

is the process whereby hydrogen atoms bind to the double bond of a compound facilitating its conversion to a single bond, in the presence of a catalyst. like palladium platinum nickel etc.

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4
Q

carbocation

A

is defined as an ion with a positively charged carbon atom that participates in various reactions such as substitution, addition and decomposition

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5
Q

key differences between Sn1 reactions and Sn2 reactions

A

Sn1 are a two step mechanism including the creation of a carbocation intermediate. Sn2 reactions are a one step mechanism involving the direct attack of the nucleophile on the substrate.

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6
Q

steps in which Sn1 reactions occur

A

1.formation of the carbocation: the leaving group departs, forming a carbocation intermediate.

2.nucleophilic attack: the nucleophile attacks the carbocation to form the final product

3.they are slow and depend on the carbocation step.

  1. examples are tertiary haloalkanes
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7
Q

steps involved in Sn2 reactions

A
  1. occurs in a single step where the nucleophile attacks the substrate and the leaving group departs simultaneously
  2. This results in a transition state where the substrate is partially bonded to both the nucleophile and the leaving group.
  3. example would be primary haloalkanes
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