Organic basics and pathways Flashcards
Substitution reactions
- Alkane and Cl2→ Halo alkane (UV light)
- Halo alkane + NaOH→ alcohol (no reagent needed)
Addition reactions
- Alkene + H2 → Alkane (catalyst)
- Alkene + Cl2 → Haloalkane
- Alkene + H2O → Alcohol (H3PO4, 300 degrees)
Oxidation of alcohols
H+/Cr2O7 -2
H+/MnO4 -
Condensation reaction
- When to molecules with different functional groups, react to form a larger molecule and smaller molecule with different functional groups
- Basically when an ester is made
- Water is a byproduct
- need H2SO4 (l)
Hydrolysis
- opposite of condensation
- requires, water to break them down
Naming priorities
In data book
4 different types of R groups
- Polar
- Non-polar
- Proton donor (COOH)
- Proton acceptor (NH2)
Protein structures and thier bonding
Primary structure- only focuses on the sequencing on Amino acids
Secondary structure- focuses on the hydrogen bonding between the amide links
Tertiary structure- intermolecular forces between r groups also;
1. Ionic
2. Covolant
Quaternary structure- dispersion forces between large molecules
Changes of pH for Amino Acids
In a base, COOH cts as an acid and looses all it hydrogens
In an acid, NH2 gains a H and turn +
Temp on enzyme
increasing temp denatures it
decreasing just slows it down
Monosacharides
- Clucose
- Fructose
- Galactose
Disachrides
- Maltose
- Sucrose
Polysacharides
- Starch
1. Amylose
2. Amylopectin - Cellulose
- Glycogen
Digestion of food
Carb-
1. Hydroylsis
2. breaks down
Protien-
1. Hydroylsis
2. breaks down
Fats-
1. Hydroylsis
2. Bile increases the surface of fats, to increase rate of reaction
3. breaks down