Organic - Alkanes Flashcards

1
Q

what is crude oil?

A

a mixture of different hydrocarbons

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2
Q

why can crude oil be separated into the separate molecules by fractional distillation?

A

as the different chains lengths of molecules result in them having different boiling points

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3
Q

by what process can crude oil be separated into the separate molecules?

A

fractional distillation

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4
Q

how does the temperature change moving up a fractioning column?

A

it is hottest at the bottom and cooler at the top

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5
Q

where in the column do shorter chain hydrocarbons condense? why?

A

high up the column because they have lower boiling points

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6
Q

where in the column do longer chain hydrocarbons condense? why?

A

nearer the bottom because they have lower boiling points

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7
Q

after fractional distillation, what happens to the products to break them down further?

A

cracking

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8
Q

why are hydrocarbons cracked?

A

to turn longer carbon chains into more useful smaller molecules

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9
Q

why are harsh reaction conditions required for cracking?

A

because C-C bonds are broken

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10
Q

what are the 2 main types of cracking?

A

thermal cracking
catalytic cracking

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11
Q

what are the main products of thermal cracking?

A

high proportion of alkanes and alkenes

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12
Q

what are the conditions for thermal cracking?

A

high temperature (around 1200 K)
high pressure (around 7000 kPa)

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13
Q

what are the main products of catalytic cracking?

A

aromatic compounds with carbon rings

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14
Q

what are the conditions required for catalytic cracking?

A

lower temperatures (than thermal) (around 720 K)
normal pressure
zeolite catalyst

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15
Q

why do alkanes make good fuels?

A

they release a lot of energy when burned

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16
Q

with sufficient oxygen, how do alkanes combust? what are the products?

A

completely
carbon dioxide and water

17
Q

with insufficient oxygen, how do alkanes combust? what are the products?

A

incompletely
carbon monoxide and water

18
Q

what harmful by-products of combustion are removed by a catalytic converter?

A

carbon monoxide
oxides of nitrogen

19
Q

what metal is the catalyst in a catalytic converter?

A

rhodium or platinum

20
Q

what does a catalytic converter convert harmful products into?

A

more stable ones such as CO₂ or H₂O

21
Q

what are carbon particulates?

A

small fragments of unburned hydrocarbon

22
Q

how are carbon particulates harmful?

A

respiratory problems
atmospheric pollutant

23
Q

how are sulphur impurities harmful?

A

react in the air leading to the acidification of water in the atmosphere, forming a weak form of sulphuric acid, acid rain

24
Q

by what process can sulphur impurities be removed from waste products after combustion?

A

flue gas desulphurisation

25
Q

how are halogenoalkanes produced?

A

alkanes reacting with halogens in the presence of UV light

26
Q

what are the 3 steps of chlorination of alkanes?

A

initiation, propagation, and termination