Inorganic - Periodicity Flashcards
what do all elements along a period have in common?
the same number of electron shells
what do all elements down a group have in common?
same number of outer electrons
which groups are in the s-block?
groups 1 and 2
which groups are in the p-block?
groups 3 to noble gases (8/0)
which elements are in the d-block?
transition metals
which elements are in the f-block?
radioactive elements
what is the trend in atomic radius along a period?
decreases
why does atomic radius decrease along a period?
- increased nuclear charge means the outer electrons are pulled in closer to the nucleus
- increased charge produces a greater electrostatic attraction, therefore atomic radius is decreased
what is the trend in atomic radius down a group?
increases
why does atomic radius increase down a group?
- an electron shell is added each time
- increasing the distance between the outer electrons and nucleus and the shielding
- therefore reducing the strength of the electrostatic force and so atomic radius increases
what is the trend in ionisation energy along a period?
increases
why does ionisation energy increase along a period?
- decreasing atomic radius and increasing nuclear charge
- so the strength of the electrostatic force is increased
- therefore more energy is required to remove the outer electron
what is the trend in ionisation energy down a group?
decreases
why does ionisation energy decrease down a group?
- electrostatic attraction between the nucleus and outer electrons decreases and shielding increases
- therefore less energy is required to remove the outer electron
what kind of bonding do sodium, magnesium, and aluminium have?
metallic
why do the melting points from sodium to magnesium to aluminium increase?
- each has a greater positive charged ion and more electrons released to the sea of delocalised electrons
- so the electrostatic forces increase from Na to Al
- therefore requiring more energy to overcome
what kind of structure does silicon have?
giant covalent structure
why does silicon have a very high melting point?
- the silicon atoms are held by strong covalent bonds in a tetrahedral structure
- these bonds require a lot of energy to overcome, giving it a high melting point
what kind of structural molecules are phosphorous, sulphur, and chlorine?
simple covalent molecules held with weak Van der Waals forces
why do phosphorous, sulphur, and chlorine have low, similar melting points?
they are held together by weak Van der Waals forces which only require a little energy to overcome