Organic 1: Introduction Flashcards

1
Q

define empirical formula

A

simplest whole number ratio of atoms in a molecule

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2
Q

define molecular formula

A

gives the actual number of atoms of different elements in a molecule

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3
Q

define displayed formula

A

shows every atom and every bond in a molecule

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4
Q

define structural formula

A

shows the arrangement of atoms in a molecule without showing every bond

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5
Q

define skeletal formula

A

drawn as lines with each vertex being a carbon atom. carbon atoms not drawn, assumed each C atom has all unspecified bonds as C-H

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6
Q

suffix for no double bonds

A

-ane

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7
Q

suffix for at least one double bond

A

-ene

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8
Q

suffix for an alcohol

A

-ol

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9
Q

suffix for an aldehyde

A

-al

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10
Q

suffix for a ketone

A

-one

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11
Q

suffix for carboxylic acid

A

-oic acid

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12
Q

prefix for one carbon in carbon chain

A

meth-

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13
Q

prefix for two carbon in carbon chain

A

eth-

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14
Q

prefix for three carbon in carbon chain

A

prop-

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15
Q

prefix for four carbon in carbon chain

A

but-

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16
Q

prefix for five carbon in carbon chain

A

pent-

17
Q

prefix for Cl group

A

chloro-

18
Q

prefix for Br group

A

bromo-

19
Q

prefix for I group

A

iodo-

20
Q

define structural isomerism

A

when molecules have the same molecular formula but different structural formula

21
Q

what is positional isomerism?

A

functional group is attached to main chain at different place

22
Q

what is functional group isomerism

A

same atoms but a different functional group due to a different arrangement of atoms

23
Q

what is chain isomerism?

A

hydrocarbon chain organised differently

24
Q

define stereoisomerism

A

when molecules have the same structural and molecular formula, but have a different arrangement of atoms in space

25
Q

what is E-Z isomerism and how are the E and Z isomers decided?

A

E-Z isomerism is caused by the limited rotation about C=C double bonds
If the two substituents with the highest molecular mass are on the same side of the double bond, is it a Z (zusammen) isomer
If they are on different sides, it is the E (entgegen) isomer