Optical Isomers Flashcards

1
Q

What is an optical isomer?

A
  • Same molecular and semi-structural formula, different spiral arrangements
  • Type of enantiomer
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2
Q

What is chirality?

A
  • Optical Isomers are chiral
  • When image is mirrored, and mirrored image cannot be superimposed on top of each other
  • i.e. cannot be rotated to look the same
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3
Q

When are organic molecules chiral?

A
  • When they have a carbon with four different side chains
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4
Q

Enantiomers/Stereoisomers:

A
  • A pair of chiral molecules that exist in two forms that are mirror images of each other, but cannot be superimposed
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5
Q

There are three possible outcomes for different enantiomers?

A
  • One enantiomer is more effective than the other
  • Each enantiomer has a different effect on the body
  • One enantiomer is effective, one is harmful
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6
Q

When does a molecule have optical isomers?

A
  • When it has a chiral carbon…
  • Meaning it is superimposable
  • Meaning it has for unique groups attached to that carbon
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7
Q

If enzymes do not contain their correct optical isomer…

A
  • The primary structure is altered
  • Active site is changed meaning that enzyme cannot do work on substrate
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8
Q

Do two stereoisomers have the same melting point?
Why?

A
  • Yes
  • Same molecular properties
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