Cells Flashcards
What happens in a galvanic cell?
1) The negative electrode (anode) corrodes due to oxidising
2) The oxidation of the anode cause electrons to be produced and head toward the cathode
3) Electrons are accepted by free roaming ions in the cathodes half cell electrolyte, and these ions collide with the cathode
4) Metal forms on the cathode due to reduction
Advantages of Hydrogen Fuel Cell
- High energy conversion efficiency
- Low pollution, hence low greenhouse emission
- No moving parts: Quiet
- Low maintenance
- Can be made a variety of sizes
Disadvantages of Hydrogen fuel cells
- Electrodes expensive
- Very little infrastructure
- Sustainability dependent on source of hydrogen
- Storage of hydrogen = problematic
Fuel Cells vs Galvanic cells:
What are the similarities?
- Involves spontaneous reactions
- Has electrolyte
- Converts chemical energy to electrical energy
Fuel Cells vs Galvanic Cells:
What are the differences?
- Fuel Cell reactants must be continuously supplied
- Fuel cells use porous electrodes to allow diffusion and increase in surface area
- Usually gaseous
Does an electrolytic cell convert chemical energy to electrical energy, or electrical energy to chemical energy
- Electrical energy to chemical energy
Do Galvanic cells convert chemical energy to electrical energy, or electrical energy to chemical energy
Chemical energy to electrical energy
If two electrolytic cells are plugged into the same power supply, the gas produced by the cells is…
Why?
- The same for both anodes
- Same circuit, means same amount of electrons passed through, means same amount of gas
Characteristics of primary cells
- Disposable
- Not designed to be recharged
Characteristics of secondary cells
- Rechargeable
- Designed to be reused
- Acts as both galvanic and electrolytic cell
What way is electron flow in discharge?
- Anode to Cathode
What way is electron flow in recharge?
- Anode to Cathode
What happens to the cell when changing from discharge to recharge
- The oxidation and reduction reactions swap
- NOT THE POLARITY
- Anode is now on positive side
- Cathode is now on negative side
- Electron flow, as always, from anode to cathode.
- Power source forces electrons into the negative electrode
- Reverses flow of electrons to cause non-spontaneous redox reaction to restore original reactants
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What is electrolysis?
- Process of converting electrical energy to chemical energy so non-spontaneous redox reaction can occur.