OG unit 1.5 Flashcards

1
Q

How are the crystal coordination numbers defined?

A

Number of nearest ions to each other ions + vice versa

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2
Q

How to say the crystal structure for sodium chloride?

A

6 ions around each other ion therefore it has a 6.6 coordination

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3
Q

What’s the name for sodium chloride’s crystal structure?

A

[interlocking?] face? centre cubic

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4
Q

Why is caesium chloride’s structure called body-centred cubic? (bcc)

A

Well in the cube, there’s one singular caesium ion and each corner of the cube consists of chloride

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5
Q

What does sodium chloride + caesium chloride have in common?
(structure and bonding)

A

It’s said to be giant and the bonding is ionic

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6
Q

What’s the melting point for strong ionic bonds?

A

Lot’s of heat req. = very high mp

Strong force of attraction between oppositely charged ions

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7
Q

What’s the conductivity for strong ionic bonds?

A

Zero as the solid ions fixed in a lattice.
However they can conduct if molten/dissolved in water as ions free to move + carry current

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8
Q

What’s the hardness for strong ionic bonds?

A

Hard but brittle. Can be cleaved easily (breaks crystal lattices)

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9
Q

Define allotrope

A

Different forms of the same chemical element

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10
Q

Properties of Graphite?
(6 things)

A
  • High m.p, lots of heat req to break covalent bonds
  • 4 valence (outer most shell) what da frick does that mean
  • 3/4 e- used in bonding
  • 1 free e- to move (delocalised) + carry electrical current
  • Hexagonal layers of carbons connected to 3 other carbons by strong covalent bonds
  • Layers held together by weak intermolecular forces that can easily be overcome = layers slide off easily past each other
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11
Q

Use of Graphite and why?

A

Lubricants and pencils
Cuz it’s slippery and soft

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12
Q

1 thing in common of diamond and graphite?

A

Very high mp due to very strong covalent bonds

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13
Q

What structure and bonding of diamond + graphite?

A

The structures are said to be giant and the bonding is covalent

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14
Q

Properties of Diamond?
(Only 3 things)

A

Technically similar to graphite but wayy stronger because:
- Each carbon atom bonded to 4 others, forming 3-dimensional structure (a tetrahedral structure)
- Has stronger intramolecular bonds = more energy req to overcome bonds
- 0 electrical conductivity compared to graphite cuz no free e- to carry the current

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15
Q

Use of diamond and why?

A

Drill bit cuz like
it’s rlly strong

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16
Q

wat 3 other forms of carbon?

A
  • Buckminsterfullerene
  • Graphene
  • Carbon nanotubes

This may be needed im not sure but if it is in there, just know u have failed miserably

17
Q

What happens when iodine is heated?

A

Turns into gas
(was this rlly needed? welp the more u know)

18
Q

What type of structure is iodine? and why it got strange property of it to turn into gas or something like that?

A
  • Face-centred cubic
  • Has weak VDW forces
19
Q

Explain ice’s structure or summin like that
(3 things)

A
  • Hydrogen bonds between water molecules hold them together
  • In a fairly open tetrahedral structure
  • Strong bonds within the water molecules are polar covalent
20
Q

What’s the ‘electron sea’ model for bonding in metals?

A

That lattice drawing thingy majiggy:

  • Neat rows of positive metal ions
  • Electrons free to move (delocalised) and carry on electric current
21
Q

What structure and bonding of them metals?

A

Giant, metallic

22
Q

How can metals differ?

A

Different number of ion charges = different number of delocalised electrons

23
Q

How do metals conduct electricity?

A
  • Plenty of delocalised electrons
  • Free to move and carry current
24
Q

How does metal have high melting & boiling points?

A
  • Strong electrostatic attraction
  • Between oppositely charged particles

(ion + electron = metallic bonds)
^ idk, this was in the book

25
Q

Define malleable?

A

Easily shaped

26
Q

Define ductile?

A

Easily stretched into wires or summin?

27
Q

How can metals exhibit malleable/ductile properties?

A
  • Arranged in neat rows (bonding)
  • Can easily slide past each other
28
Q

Properties of giant ionic compounds (such as the chlorides)?

Just do last 4

A

Generally:
- Hard
- Brittle
- High mp due to strong ionic bonds

  • No electrical conductivity in solid state, ions fixed in position
  • Conducts when molten/aqueous solutions (ions free to move and carry electric current)
  • Can sometimes not be solube in water depending on energetics/chemical reaction factors, but most ionic chlorides are soluble
29
Q

2 giant covalent compounds?
and 1 new info

A

Diamond and graphite

  • Insoluble in water
30
Q

Info of simple covalent compounds? (iodine)

A
  • Doesn’t conduct electricity (no free electrons)
  • Soft and volatile (easily evaporated) due to iodine molecules held together by weak Van de Waal’s forces
31
Q

Additional info of metallic bonding?
(only do last 2)

A

Delocalised electrons:
- Allow to conduct an electrical current
- Allows good thermal conductivity

  • Melting temp & hardness increases
  • With number of electrons per atom involved with bonding
32
Q

Lastly, it’s all about gathering questions to respond to

A

Alright