Nuclear Chemistry Flashcards

1
Q

In his experiments, he exposed certain salts—among them uranium salts—to sunlight for several hours, whereupon they phosphoresced.

A

Henri Becquerel

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2
Q

Three kinds of radiation

A

alpha, beta, gamma

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3
Q

helium nuclei

A

Alpha particles

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4
Q

are electrons. Each has a charge of 21.

A

Beta particles

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5
Q

are high-energy electromagnetic radiation.

A

Gamma rays

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6
Q

the distance from one wave crest to the next.

A

wavelength

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7
Q

the number of crests that pass a given point in one second.

A

frequency

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8
Q

Electromagnetic radiation comes in packets; the smallest units are called

A

photons

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9
Q

are electromagnetic radiation of very high frequency (and high energy).

A

Gamma rays

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10
Q

are electromagnetic radiation of very high frequency (and high energy).

A

Gamma rays

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11
Q

has frequencies (and energies) higher than those of visible light but less than those of gamma rays.

A

X-rays

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12
Q

Materials that emit radiation (alpha, beta, or gamma) are called

A

radioactive

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13
Q

A radiation emitting isotope of an element

A

Radioactive isotopes

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14
Q

A reaction that changes atomic nuclei of elements
(usually to atomic nuclei of other elements)

A

Nuclear reaction

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15
Q

The proton remains in the nucleus but the electron is emitted from it.

A

Beta emission

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16
Q

The changing of one element into another is called

A

transmutation

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17
Q

emits both an a particle and gamma rays

A

Polonium-210

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18
Q

Is a particle that has the same mass as an electron, but a charge of 11 rather than 21.

A

Positron

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19
Q

often accompanies a and b emissions

A

Gamma emission

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20
Q

an extranuclear electron is captured by the nucleus and there reacts with a proton to form a neutron.

A

Electron capture

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21
Q

The time it takes for one half of any sample of radioactive material to decay is called the

A

Half-life

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22
Q

most of the radioactivity disappears
after _______ by that time, only _____ of the original remains

A

5 half-lives, 3%

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23
Q

After ______ half-lives, less than _______ of the activity remains.

A

10, 0.1%

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24
Q

The half-life of an isotope is independent of

A

temperature and pressure

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25
When these rays interact with matter, they usually knock electrons out of the electron cloud surrounding an atomic nucleus, thereby creating positively charged ions from neutral atoms.
Ionizing radiation
26
Ionizing radiation is characterized by two physical measurements
Intensity and energy
27
which is the number of particles or photons emerging per unit time
Intensity
28
Instruments used to measure intensity
Geiger-Muller counter and proportional counter
29
material called a phosphor that emits a unit of light for each alpha or beta particle or gamma ray that strikes it.
Scintillation counters
30
A commonly used unit of radiation intensity is the
Curie
31
much smaller, unit of radiation activity (intensity) is the
Becquerel
32
beta particles have an energy range of
1 to 3 MeV
33
the least penetrating; they can be stopped by several sheets of ordinary paper, by ordinary clothing, and by the skin
Alpha particles
34
have greater penetrating power; They can penetrate several millimeters of bone or tissue.
Beta particles
35
is the most penetrating of the three types of radiation. They can pass completely through the body
Gamma radiation
36
when in the body, are more damaging, however
Alpha particles
37
are a measure of the energy delivered by a radiation source and are, therefore, a measure of exposure to a particular form of radiation.
Roentgens
38
which stands for radiation absorbed dose, is a measure of the radiation absorbed from a radiation source.
Rad
39
SI unit of rad
Gray = 100 rad
40
which stands for roentgen equivalent for man, is a measure of the effect of the radiation when a person absorbs 1 roentgen.
Rem
41
SI unit for rem
sievert = 100 rem
42
Naturally occurring radiation
background radiation
43
is the most widely used aspect of nuclear medicine.
Medical imaging
44
This method is based on the property that certain isotopes (such as carbon-11 and fluorine-18) emit positrons
Positron emission tomography
45
is used in the treatment of prostate cancer.
Iodine-25
46
The fusion of two hydrogen nuclei into a helium nucleus liberates a very large amount of energy in the form of photons
Fusion
47
Uncontrolled fusion is employed in the
Hydrogen bomb
48
are artificial and have been prepared by a fusion process in which heavy nuclei are bombarded with light ones.
Transuranium elements
49
Transuranium elements
elements with atomic numbers greater than 92
50
fragmentation of large nuclei into smaller pieces
Nuclear fission
51
The most important product of this nuclear decay is energy, which results because the products have less mass than the starting materials.
Atomic energy
52
If even one of these neutrons produces a new fission, the process becomes a self-propagating _______ that continues at a constant rate.
Chain reaction
53
is the combining (fusing) of two lighter nuclei to form a heavier nucleus.
Nuclear fusion
54
results from the bombardment of nuclei by neutrons, protons, or other nuclei.
nuclear transmutation
55
like charges repel and unlike charges attract one another.
Coulomb's law
56
The principal factor that determines whether a nucleus is stable is the
neutron to proton ratio
57
The numbers 2, 8, 20, 50, 82, and 126 are called
magic numbers
58
Rules in predicting nuclear stability
1. Magic numbers for proton and neutrons 2. Even numbers of proton and neutron are more stable than odd numbers 3. All isotopes with atomic number higher than 83 are radioactive
59
The stable nuclei are located in an area of the graph known as the
belt of stability
60
the energy required to break up a nucleus into its component protons and neutrons.
Nuclear binding energy
61
which is a general term for the protons and neutrons in a nucleus.
nucleons
62
The difference between the mass of an atom and the sum of the masses of its protons, neutrons, and electrons is called
mass defect
63
a sequence of nuclear reactions that ultimately result in the formation of a stable isotope
radioactive decay series
64
uses electric and magnetic fields to increase the kinetic energy of charged species so that a reaction will occur
Particle accelerator
65
The first nuclear fission reaction to be studied was that of
Uranium-235
66
the minimum mass of fissionable material required to generate a self-sustaining nuclear chain reaction
critical mass
67
Most of the nuclear reactors in the United States are
light water reactors
68
substances that can reduce the kinetic energy of neutrons.
moderators
69
it eliminates the need for building expensive uranium enrichment facilities.
Heavy water reactors
70
uses uranium fuel, but unlike a conventional nuclear reactor, it produces more fissionable materials than it uses
Breeder reactor
71
are dangerous radioactive isotopes with long half-lives
Strontium-90
72
used as a nuclear fuel and produced in breeder reactors, is one of the most toxic substances known.
Plutonium-239
73
fusion reactions take place only at very high temperatures, they are often called
thermonuclear reactions
74
state of matter, a gaseous mixture of positive ions and electrons
plasma
75
Isotopes, especially radioactive isotopes that are used to trace the path of the atoms of an element in a chemical or biological process
tracers
76
molecular fragments having one or more unpaired electrons; they are usually short lived and highly reactive.
radicals