Nitrogen Flashcards
Potential green house has
N2O (270x times more effective than CO2)
Most potent destroyer of ozone
Nitrous oxide
How have we added more nitrogen to the environment
Fertilizers
(That fixes nitrogen to ammonia )
Also by nitrogen fixers that are human managed
Burning fossil fuels to NO
Acid rain - NO major component
Effect of increase in nitrogen pool
Algal blooms in lakes and marine ecosystem, contamination of ground water but also high agricultural yield
Fixing of atmospheric nitrogen
N2+ 8H +8e +16ATP => 2NH3+H2+16ADP(biological nitrogen fixation - rhizobium , anabena)
Industrial nitrogen fixation:
Fertilizers such as urea
Atmospheric nitrogen:
Lightening breaks atmospheric nitrogen
Energy costs of breaking triple bond is very high
Nitrogenase has two complex proteins
Dinitrogenase reductase and dinitrogenase
Dinitrogenase reductase coded by
nifH genes
Mo-Fe protein has
Any Fe atoms and two Mo atoms
Strategies to seperate oxygen from nitrogen production
Heterocysts to prevent oxygen from interfering with nitrogenase activity
High oxygen rates are maintained to consume oxygen
Nitrification
Ammonia converted to nitrate
(NH3 + O2 => NO2- +H + H2O)
Nitrosomonas
NO2- + O2 => NO3-
Ammonification
When organic mass of dead and decaying matter decomposers convert to ammonis
Denitrification
Convert nitrate to gaseous nitrogen
Clostridium, pseudomonas they process the nitrate to gain oxygen and as by product release nitrogen gas
Frankia colonized ….
Actinorhizal plants enabling them to survive in fertile soils
Conversion of ammonia to nitrate
Requires 34 moles of NH3+ to fix 1 mole of CO2
Nitrite to nitrate
Nitrite oxidising organisms require 100 moles of NO2- to 1 mole CO2
Archael counterparts of nitrosomonas nitrobacter
Nitrisipumilus , nitrisisphaera
rate-limiting step of nitrification.
conversion of ammonia into nitrite
Liebig Mineral theorem
crips growth on afield reflects the exact proportion of diminition or increase of minerals conveyed to it in manure. So it stresses the value of minerals derived from soil and the need of replacing them for soil fertility.
same as limiting nutruent will determine yield