Navigating the periodic table Flashcards

1
Q

periodic table

A

system of organising the 118 known elements based on recurring patters

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2
Q

how did Mendeleev organise his table?

A
  • groups vertically
  • left gaps
  • did not know about electron config
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3
Q

elements with same valence electrons?

A

same properties

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4
Q

matter

A

atoms bonded together

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5
Q

reactions happen when…

A

bonds between atoms break and reform in new arrangements

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6
Q

what are involved in bonds?

A

electrons

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7
Q

core electrons

A

inner electrons that do not bond

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8
Q

how are electrons arranged in shells?

A

2, 8, 8, 18, 18, 32, 32

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9
Q

why does a full shell make an atom stable?

A

lots of energy required to remove or add electrons

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10
Q

ionic bonds - define and what do they form?

what type of bond is it?

A

one elements gives up an electron (cation) and one accepts (anion). they are attracted to their opposite charges and form a lattice.
electrostatic

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11
Q

covalent bonds

A

the sharing of electrons between atoms. some can share multiple ways.

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12
Q

define molecule

A

groups of atoms that share electrons covalently

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13
Q

cation + anion =

A

salt

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14
Q

how is the cation named?

A

as the element is eg. magnesium

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15
Q

how is the anion named?

A

one element ends in ide

if there is an oxygen it is ite or ate

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16
Q

what shields nucleuses from each other in covalent bonding?

17
Q

what are the electrostatic interactions in covalent bonding?

A

attraction - between electrons and nucleus

repulsion - between electrons and between nuclei

18
Q

how to name covalent bonds?

A

first element is just its name
second takes the stem of the name and adds ide
prefixes indicate number of atoms

19
Q

bonding continuum?

A

more of a continuum then ionic and covalent

20
Q

explain how bonds break and from

A
  • making bonds releases energy (lower energy arrangement)
  • breaking bonds requires energy (pull)
  • net energy released from bond formation
21
Q

how does electronic configuration work?

A

nS^2np^6
n is shell number
s, p, d are the orbitals
numbers are number of electrons

22
Q

What are formal charges and what do they need to be?

A
  • a representation of how charge is distributed
  • needs to be 0 or close
  • in a neutral molecule all atoms should be 0
23
Q

equation for formal charge

A

FC = number of valence electrons central atom has - (number of lone pairs + 1/2 bonding electrons)

24
Q

steps for drawing lewis diagrams

A
  • determine number of valence electrons
  • arrange atoms around a central atom and give each atom set a single bond
  • beginning with terminal atoms, add enough electrons to each atom to give the atom an octet
  • place any left over electrons on central atom
  • minimise formal charges by making double and triple bonds
25
physical and chemical geometry alters properties such as
- melting point - polarity - boiling point
26
2 electron domains
- linear (no lone pairs on central atom)
27
three electron domains
- trigonal planar | - bent
28
4 electron domains
- tetrahedral - trigonal pyramidal - bent
29
5 electron domains
- trigonal bipyramidal - disphenoidal (4 terminal atoms) - T shaped - linear
30
6 electron domains
- octahedral (6 terminal atoms) | - square planar (4 terminal atoms)
31
VSEPR
model that predicts shape of molecules by putting valence electrons far away to minimise repulsion
32
linear degrees
180
33
trigonal planar degrees
120
34
tetrahedral degrees
109.5
35
trigonal bipyramidal degrees
90 and 120 (horizontally)
36
octahedral degrees
90
37
which angle is bigger? single, double or triple bond
triple (more repulsion)
38
parent geometry?
overarching shape
39
molecular geometry?
specific