Navigating the periodic table Flashcards

1
Q

periodic table

A

system of organising the 118 known elements based on recurring patters

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2
Q

how did Mendeleev organise his table?

A
  • groups vertically
  • left gaps
  • did not know about electron config
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3
Q

elements with same valence electrons?

A

same properties

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4
Q

matter

A

atoms bonded together

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5
Q

reactions happen when…

A

bonds between atoms break and reform in new arrangements

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6
Q

what are involved in bonds?

A

electrons

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7
Q

core electrons

A

inner electrons that do not bond

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8
Q

how are electrons arranged in shells?

A

2, 8, 8, 18, 18, 32, 32

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9
Q

why does a full shell make an atom stable?

A

lots of energy required to remove or add electrons

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10
Q

ionic bonds - define and what do they form?

what type of bond is it?

A

one elements gives up an electron (cation) and one accepts (anion). they are attracted to their opposite charges and form a lattice.
electrostatic

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11
Q

covalent bonds

A

the sharing of electrons between atoms. some can share multiple ways.

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12
Q

define molecule

A

groups of atoms that share electrons covalently

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13
Q

cation + anion =

A

salt

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14
Q

how is the cation named?

A

as the element is eg. magnesium

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15
Q

how is the anion named?

A

one element ends in ide

if there is an oxygen it is ite or ate

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16
Q

what shields nucleuses from each other in covalent bonding?

A

electrons

17
Q

what are the electrostatic interactions in covalent bonding?

A

attraction - between electrons and nucleus

repulsion - between electrons and between nuclei

18
Q

how to name covalent bonds?

A

first element is just its name
second takes the stem of the name and adds ide
prefixes indicate number of atoms

19
Q

bonding continuum?

A

more of a continuum then ionic and covalent

20
Q

explain how bonds break and from

A
  • making bonds releases energy (lower energy arrangement)
  • breaking bonds requires energy (pull)
  • net energy released from bond formation
21
Q

how does electronic configuration work?

A

nS^2np^6
n is shell number
s, p, d are the orbitals
numbers are number of electrons

22
Q

What are formal charges and what do they need to be?

A
  • a representation of how charge is distributed
  • needs to be 0 or close
  • in a neutral molecule all atoms should be 0
23
Q

equation for formal charge

A

FC = number of valence electrons central atom has - (number of lone pairs + 1/2 bonding electrons)

24
Q

steps for drawing lewis diagrams

A
  • determine number of valence electrons
  • arrange atoms around a central atom and give each atom set a single bond
  • beginning with terminal atoms, add enough electrons to each atom to give the atom an octet
  • place any left over electrons on central atom
  • minimise formal charges by making double and triple bonds
25
Q

physical and chemical geometry alters properties such as

A
  • melting point
  • polarity
  • boiling point
26
Q

2 electron domains

A
  • linear (no lone pairs on central atom)
27
Q

three electron domains

A
  • trigonal planar

- bent

28
Q

4 electron domains

A
  • tetrahedral
  • trigonal pyramidal
  • bent
29
Q

5 electron domains

A
  • trigonal bipyramidal
  • disphenoidal (4 terminal atoms)
  • T shaped
  • linear
30
Q

6 electron domains

A
  • octahedral (6 terminal atoms)

- square planar (4 terminal atoms)

31
Q

VSEPR

A

model that predicts shape of molecules by putting valence electrons far away to minimise repulsion

32
Q

linear degrees

A

180

33
Q

trigonal planar degrees

A

120

34
Q

tetrahedral degrees

A

109.5

35
Q

trigonal bipyramidal degrees

A

90 and 120 (horizontally)

36
Q

octahedral degrees

A

90

37
Q

which angle is bigger? single, double or triple bond

A

triple (more repulsion)

38
Q

parent geometry?

A

overarching shape

39
Q

molecular geometry?

A

specific