natural polymers Flashcards
cellulose
repeat 1,4B
difficult to process
traditional viscose method use of CS2
new cellulose solvents = ionic liquid, NaOH/urea
starch
repeating graph 1,4 and 1,6
liner amylase and branched amylopectin
gelatinization
poor wet mechanical properties
chitin
deacetylation using sodium hydroxide
antibacterial and anti-inflammatory
natural polymers
cellulose chitin starch perotein chitin chitosan alginic acid hyaluronic acid xanthan gum curdlan
bioplastics
biopolymers shaped bua plasticization or cross linking PLA in corn PHA form bacteria port based =casein starch based = cereplast vegetable oil = soyoyl
problem of disposable plastics
limited recycling options
limited landfill space
incineration may release toxin
synthetic plastic exacerbate dependance on fossil fuel
advantage of biopolymers
renewable livestock domestically grown CO2 neutral biodegradbale biocompatible energy saving
disadvantages
more expensive
low end mechanical properties
lower service temperature
not as durable
advantages of wheat gluten
film forming low price biodegradable non toxic adhesive gas barrier and selectivity very high selectivity
drawbacks
poor water resistance
poor mechanical properties
natural polymers nanocrystal
reinforcing mechanical propertjes improve barrier properties stabilizing food emulsion swelling properties thermal stability