mtn4 Flashcards
Which of the following can be calculated theoretically using
steam table and Dalton’s law of partial pressure; if the relative
humidity and dry bulb temperature of moist air is known?
A. Dew point
B. Humidity ratio
C. Wet bulb temperature
D. None of these
C
Which of the following is the correct ternary diagram for liquid
liquid extraction system comprising of two pairs partly soluble
(e.g., chlorobenzene-water-methyl ethyl ketone system)?
A
Steam distillation is used for separation of high boiling
A. substances from non-volatile impurities.
B. volatile impurity from still higher boiling substances.
C. both (a) and (b).
D. neither (a) nor (b).
C
The slope of 9-line is determined by the
A. reflux ratio
B. plate efficiency to be achieved
C. thermal condition of the feed
D. relative volatility.
C
The feed to fractionating column is changed from saturated
vapour to saturated liquid. If the separation and reflux ratio
remains unchanged, the number of ideal stages will
A. increase
B. decrease
C. remains same
D. depend on saturated boiling point; may increase or
decrease
A
Rose oil is extracted from rose leaves using _______ distillation.
A. high pressure
B. low pressure
C. extractive
D. steam
D
Rose = steam
Hypersorption refers to a __________ process.
A. fixed bed absorption
B. moving bed absorption
C. fixed bed adsorption
D. moving bed adsorption
D
Extraction of coffee from its seed is done by
A. liquid-liquid extraction.
B. leaching.
C. extractive distillation.
D. steam distillation.
B
In azeotropic mixture, the equilibrium vapour composition is
A. more than liquid composition.
B. less than liquid composition.
C. same as liquid composition.
D. independent of pressure.
C
(Eq = same)
With lapse of time, the overhead composition of light component
in case of batch distillation with constant reflux
A. increases
B. decreases
C. remains same
D. may increase or decrease ; depends on system.
B
lapse = decrease
According to the film theory of mass transfer, the mass transfer
co-efficient is proportional to (where, D = molecular diffusivity)
A. D
B. D2
C. D0.5
D. 1/D
A
Dry bulb temperature of the gas is _____ the wet bulb temp.
A. less than
B. more than
C. equal to
D. none of these
B
Decoction refers to the use of solvent
A. at ambient temperature
B. at its boiling point
C. in its vapor form
D. none of these
B
Flooding in a column results due to
A. high pressure drop
B. low pressure drop
C. low velocity of the liquid
D. high temperature
A
Flash distillation is suitable for separating the constituents of a
binary system, which
A. form minimum boiling azeotrope.
B. have very wide boiling points.
C. have very close boiling points.
D. form constant boiling azeotrope.
B
Lewis number, which is important in problems involving
simultaneous heat and mass transfer, is the ratio of
A. mass diffusivity to momentum diffusivity.
B. thermal diffusivity to mass diffusivity.
C. momentum diffusivity to thermal diffusivity.
D. none of these.
B
The ratio of Murphree plate efficiency to point efficiency is 1 in a
__________ flow model.
A. Plug
B. perfectly mixed
C. both (a) & (b)
D. neither (a) nor (b)
B
The rough value of diffusion co-efficient of water vapor into air
at 25°C may be about __________ cm2/sec.
A. 0.25
B. 2.5
C. 1.25
D. 0.0025
A
Which of the following gas-liquid contacting devices incurs the
least pressure drop for a particular duty ?
A. Grid tray tower
B. Perforated tray tower
C. Wetted wall tower
D. Bubble cap tower
C
A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%.
m-xylene (all percentages in w/w). Which of the following
statements would be true in respect of this mixture?
A. The mixture exhibits an azeotrope at 101.3 kPa.
B. The composition of the mixture, in percent by volume
is: o-xylene 30, p-xylene 60. and m-xylene 10.
C. The composition of the mixture in mole percent is: o
xylene 30, p-xylene 60 and m-xyoene 10.
D. The mixture contain optical isomers.
A
Unsaturated air (with dry bulb temperature and dew point being
35°C and 18°C respectively) is passed through a water spray
chamber maintained at 15°C. The air will be cooled
A. and humidified.
B. and dehumidified with increase in wet bulb
temperature.
C. at the same relative humidity.
D. and dehumidified with decrease in wet bulb
temperature.
D
Unit operation involved in the prilling of urea is
A. evaporation
B. drying
C. crystallization
D. both (b) and (c)
D
Pick out the wrong statement pertaining to leaching.
A. Fine solids can not be leached in a Pachuka tank.
B. Door classifier can be used for leaching of coarse
solids.
C. Vegetable seeds can be leached in either of Bollman
extractor, Rotocel or Kennedy extractor.
D. Very high temperature is not needed for the leaching of
sugar beet.
A
Molecular seives are porous
A. alumina.
B. silica.
C. synthetic zeolites crystals/metal alumino-silicates.
D. none of these.
C
The process employing desorption of the absorbed solute by a
solvent is called
A. elution
B. osmosis
C. reverse osmosis
D. sublimation
A
If the overall efficiency and Murphree plate efficiency are equal,
then both the equilibrium and operating lines are
A. straight
B. parallel
C. both (a) & (b)
D. neither (a) nor (b)
C
Which of the following operations does not involve leaching ?
A. Dissolving gold from ores.
B. Dissolving pharmaceutical products from bark or roots.
C. Dissolving sugar from the cells of the beet.
D. Removing nicotine from its water solution by kerosene.
D
The recovery of pencillin from the acidified fermentation broth is
done by
A. Distillation
B. Evaporation
C. Absorption
D. liquid extraction
D
Calcium ammonium nitrate (a fertiliser) is dried in a _____ dryer.
A. Rotary
B. Vacuum
C. Tunnel
D. Tray
A
A binary mixture of benzene and cyclohexane is separated by
A. flash vaporization
B. extractive distillation
C. solvent extraction
D. ordinary distillation
B
Component A is diffusing in a medium B. The flux NA relative to
a stationary point is = to the flux due to molecular diffusion, if
A. mass transfer is accompanied by reaction.
B. diffusion of A is in stagnant medium B.
C. molecular mean free path is high.
D. there is equimolar counter diffusion.
D
Stationary = equi
Cox chart is useful in the design of
A. distillation column
B. evaporator
C. dryer
D. crystallizer
A
Absorption factor, for a fixed degree of absorption from a fixed
amount of gas should be
A. 1
B. > 1
C. < 1
D. ≤ 1
B
Selectivity of the solvent used in solvent extraction should be
A. 1
B. > 1
C. < 1
D. 0
B
Dew point of an air-water vapor mixture
A. decreases with decrease in pressure.
B. at constant humidity & total pressure is fixed.
C. corresponding to any point on the humidity chart is
obtained by projecting a line through this point parallel
to the temperature axis and to the saturation curve.
D. all ‘a’, ‘b’ & ‘c’.
D
Can a cooling tower cool water below the wet bulb temperature
of inlet air?
A. yes
B. no
C. yes; but height of cooling tower will be prohibitively
high.
D. yes; but the air flow rate should be excessively high
B
The solvent used in liquid-liquid extraction should have
__________ less than one.
A. Selectivity
B. distribution co-efficient
C. both (a) and (b)
D. neither (a) nor (b).
D
(Less than = neither)
The suitable evaporator for concentration of foaming liquids is a
__________ evaporator.
A. long tube
B. short tube
C. vacuum
D. falling film
A
The ratio of Murphree plate efficiency to point efficiency is
always > 1 in a __________ flow model.
A. Plug
B. perfectly mixed
C. both (a) & (b)
D. neither (a) nor (b)
A
Tea percolation employs
A. liquid-liquid extraction
B. leaching
C. absorption
D. none of these
B
NSc/NPr is called the
A. psychrometric ratio
B. Lewis number
C. Sherwood number
D. Stantan number
B
McCabe-Thiele method
A. uses molal units for material and energy balance.
B. uses weight fractions to express liquid and vapour
composition.
C. can use any type of units.
D. is more accurate than Ponchan-Savarit method.
A
The film penetration model of mass transfer was enunciated by
A. Gilliland
B. Toor and Marchello
C. Stefan
D. Fick
B
film = toor
The most economical range of absorption factor is
A. 0 to 0.5
B. 0 to 3
C. 1.25 to 2
D. 5 to 15
C
Channelling is most severe
A. in towers packed with stacked packing.
B. in towers packed randomly with crushed solids.
C. in dumped packing of regular units.
D. at very high liquid flow rate.
A
Out of two equilibrium curves, first one lies above the diagonal
and the second lies below the diagonal in the x-y plot. It means
that separation by distillation is
A. not possible in the second case unless vacuum is
applied.
B. not possible in the second case unless high pressure
is applied.
C. more readily done in the second case compared to first
one.
D. none of these
C
out of two = more
ADDUCTS’ and ‘CLATHRATES’ are used in case of
A. extractive distillation.
B. crystallisation.
C. absorption.
D. none of these.
B
Adsorption is an unit operation which generally involves
__________ systems.
A. liquid-solid
B. gas-solid
C. fluid-solid
D. solid-solid
C
In case of __________ distillation, a solvent is added to alter the
relative volatility of the mixture to be separated.
A. Molecular
B. Azeotropic
C. Extractive
D. flash.
C
Separation of the isotopes of helium for scientific investigations
is done by
A. reverse osmosis
B. thermal diffusion
C. leaching
D. solvent extraction
B
In a binary system, separation is very efficient, when the relative
volatility is
A. 1
B. > 1
C. < 1
D. 0.5
B
Fenske-Underwood equation used for calculating the minimum
number of theoretical plates in distillation column is valid for
A. constant molal overflow
B. total reflux
C. constant relative volatility
D. all (a), (b) and (c)
D
The binary diffusivity in gases does not depend upon the
A. pressure
B. temperature
C. nature of the components
D. none of these
C
Berl saddle made of carbon cannot be used for
A. alkalis
B. SO2
C. H2SO4
D. oxidising atmosphere
D
1 kg of a saturated aqueous solution of a highly soluble
component A at 60°C is cooled to 25°C. The solubility limits of
A are (0.6 kgA/kg water) at 60°C and (0.2 kgA/kg water) at 25°C.
The amount in kg of the crystals formed is
A. 0.4
B. 0.25
C. 0.2
D. 0.175
C
During drying of a solid, the critical moisture content increases
with
A. decreased drying rate
B. increased thickness of the solid
C. increased drying rate
D. both (b) and (c).
D
Priming in a distillation column
A. results from very low gas velocity.
B. is desirable from point efficiency consideration.
C. is characterised by the presence of foam throughout
the space between trays.
D. reduces the overall pressure drop.
C
priming = foam
The commonly used solvent in supercritical extraction is
A. methyl ethyl ketone.
B. water.
C. carbon tetrachloride.
D. carbon dioxide.
D
(Supercritical = CO2
When the liquid over a plate is of uniform concentration, then
A. Murphree efficiency > point efficiency.
B. Murphree efficiency < point efficiency.
C. Murphree efficiency = point efficiency.
D. Murphree efficiency ≠ point efficiency.
C
In saturated gas, the
A. vapour is in equilibrium with the liquid at the gas
temperature.
B. vapour is in equilibrium with the liquid at the room
temperature.
C. partial pressure of vapour equals the vapour pressure
of the liquid at room temperature.
D. none of these
A
As per Gilliland’s equation, the diffusivity is
A. directly proportional to ‘T1.5’.
B. inversely proportional to ‘P’.
C. dependent on the molecular volume & molecular
weight of components.
D. all ‘a’, ‘b’ & ‘c’.
D
What is the degree of freedom of an absorption process in which
only one component is transferred between phases?
A. 3
B. 2
C. 4
D. 1
A
Pick out the wrong statement.
A. When the concentration difference for the mass
transfer becomes zero at the bottom of the gas
absorption tower, then the upper end of the operating
line touches the equilibrium curve.
B. The average distance between the operating line and
equilibrium line is large, when the liquid-gas ratio is
also large in case of a counter current gas absorption
tower.
C. The operating line lies above the equilibrium curve in
case of a gas desorber.
D. With decrease in the liquid flow rate for a fixed gas flow
rate, the slope of the operating line decreases, in case
of gas absorption process.
C
A mixture of 10% C6H6 vapour in air at 25°C and 750 mm Hg
has a dew point of 20°C. Its dew point at 30°C and 700 mm Hg
will be around __________ °C.
A. 21.7
B. 20
C. 27.3
D. 18.7
D
Which of the following is not fixed by the process requirements,
in the design of absorbers ?
A. Flow rate of the entering gas.
B. Composition of the entering liquid.
C. Terminal concentrations of gas stream.
D. None of these.
D
If the amount of the steam used in steam distillation is increased,
the temperature of distillation
A. Increases
B. Decreases
C. remains unchanged
D. depends on relative volatility
B
^ Steam, v temp
Moisture in a solid exerting an equilibrium vapour pressure equal
to that of the pure liquid at the same temperature is called the
__________ moisture.
A. Unbound
B. Critical
C. Free
D. Bound
A
Inside the distillation columns, the
A. highest temperatures is near the feed plate.
B. driving force for the liquid flow is its weight.
C. vapors are not always at their dew points.
D. all (a), (b) and (c)
B
When the psychometric ratio is __________ then the adiabatic
saturation temperature and wet bulb temperature becomes
equal.
A. 1
B. < 1
C. > 1
D. ∞
A
Becomes equal = 1
Desirable value of absorption factor in an absorber is
A. 1
B. < 1
C. > 1
D. 0.5
C
Refractory bricks are usually dried in a __________ dryer.
A. Tray
B. Tunnel
C. Conveyor
D. Festoon
B
For __________ drying, the effects of velocity, temperature and
humidity of the gas and the thickness of the solid are the same.
A. unsaturated surface
B. constant rate
C. both (a) and (b)
D. neither (a) nor (b).
C