Molecular Shapes Flashcards

1
Q

what is the VSPER Theory

A

valence shell electron pair repulsion theory

states that valence shell electron pairs will repel themselves as fa apart as possible in the 3D of space

the shape adopted by a simple molecule or ion is that which keeps repulsive forces to a minimum

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2
Q

bond pair repulsions angles in molecules without lone pairs

A

1 or 2 bond pairs - linear - 180 degrees
3 bond pairs - trigonal planar - 120 degrees
4 bond pairs - tetrahedral - 109.5 degrees

all bond pair bond pair repulsions are equal

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3
Q

order of repulsive power between bonds

A

LP - LP > BP - LP > BP - BP

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4
Q

how are the angles between lone pairs and bond pairs changed

A

lone pairs have greater repulsive power than bond pairs so their presence will affect (increase) the angles of the bonds as they push the bond pairs away.

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5
Q

bond pair and lone pair repulsions angles in molecules with lone pairs

A

3 BP and 1 LP
angle is 107 degrees
shape is pyramidal

2 BP and 2 LP
angle is 104.5 degrees
shape is bent

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