Molecular shape and bonding Flashcards

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1
Q

What does 𝚿 Mean

A

Wave function

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2
Q

What is 𝚿

A

A mathematical function that relates the location of an electron at a given point in space to it’s amplitude of waves

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3
Q

What is 𝚿 2

A

Electron density which is the probability of finding an electron in a specific location around an atom

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4
Q

What shape are all s orbital

A

Spherical

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5
Q

What shape is a p orbital

A

Dumbbell shaped where a node plane separates the two lobes

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6
Q

What are the three degenerate p orbitals

A

X,Y and Z

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7
Q

What does a 1s orbital look like when its 𝚿 Is plotted against distance from nucleus

A

Curved L shape

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8
Q

What is a node on the graph

A

When 𝚿 =0

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9
Q

Definition of degenerate

A

When orbital are at the same energy level

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10
Q

What is the Lewis theory about valence electrons

A

Elements in the same group have them same properties because they have the same valence electrons.

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11
Q

What is Lewis theory about ionic compounds

A

Electrons are transferred from one element to another forming ions

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12
Q

Properties of ionic compounds

A

High melting and boiling temperatures
Stronger when charge is higher
Stronger when the ion is smaller because less distance between ions.

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13
Q

How to calculate formal charge

A

No. of valance electrons - (no. of lone pairs + 1/2 no. of bonding electrons)

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14
Q

What is the non polar covalent bond electronegativity bond value

A

0.1-0.4

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15
Q

What is a polar covalent bond electronegativity bond value

A

0.5-1

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16
Q

What is a sigma bond

A

Overlap of two atomic orbitals to form a single bond

17
Q

What is a pi bond

A

When two 1/2 filled orbitals above and below a covalent bond overlap to share electrons

18
Q

What is the molecular orbital theory

A

Electron density is distributed over the whole molecule. The number of atomic orbitals is the same as the number of molecular orbitals

19
Q

What happens when two 1s hydrogen AO are combined

A

Makes 2 symmetrical molecular orbitals, one bonding MO and one antibonding MO

20
Q

What happens when two 1s hydrogen AO are combined

A

Makes 2 symmetrical molecular orbitals, one bonding MO and one antibonding MO

21
Q

What is a bonding molecular orbital

A

When 2 wave functions are added together

22
Q

What is an antibonding molecular orbital

A

When a wave function is subtracted from another

23
Q

Where are electrons most likely to be found in an antibonding orbital

A

Anywhere but the node

24
Q

Where are electrons most likely to be found in bonding orbitals

A

In between the nuclei

25
Q

Is the energy of electrons higher in their individual atoms or in their bonding MO

A

In their individual atoms

26
Q

Is the energy of electrons higher in their individual atoms or in their antibonding MO

A

Antibonding MO

27
Q

What shape and bond angle is a sp3

A

Tetrahedral and 109.5

28
Q

What shape and bonding is sp2

A

Trigonal planar, 120

29
Q

What shape and bond angle is sp

A

Linear, 180

30
Q

What is a dipole moment

A

Measure of the net polarity of a molecule