Molecular Geometry Flashcards
What properties does the shape of a molecule effect?
- shape impacts polarity which impacts intermolecular forces which impacts physical
properties - the shape of drug molecules and enzymes are responsible for their bioactivity
- the shapes of large, complex molecules can be understood by focusing on the shape
around each central atom
What is the valence shell electron pair repulsion (VSEPR) theory
The concept that electron groups (?!?) around an atom want to get as far away from one another to minimize repulsion
The maximum separation of electron groups around an interior/central atom
leads to the shape of a molecule
What can be classified as an electron group?
a single bond is one electron group
a double bond is one electron group
a triple bond is one electron group
a lone pair is one electron group
a single electron (in a radical species) is an electron group
molecular geometry
The spatial arrangement of ONLY the BONDS around a central atom
What are the possible molecular geometries in 2 electron groups
linear
What are the possible molecular geometries in 3 electron groups
trigonal planar
bent
What are the possible molecular geometries in 4 electron groups
tetrahedral
trigonal pyramidal
bent
What are the possible molecular geometries in 5 electron groups
trigonal bipyramidal
seesaw
T-shaped
linear
What are the possible molecular geometries in 6 electron groups
octahedral
square pyramidal
square planar