Acids and Bases Flashcards

1
Q

Acids

A

Ahhenius definition: Molecular compound that dissociates in water to generate H+/H3O+ ions

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2
Q

Monoprotic acid

A

Acid that can donate only one proton (H+ ion) per molecule in solution

ex. HCL, HNO3 (nitric acid), CH3COOH (acetic acid)

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3
Q

Diprotic acids

A

Can donate two protons H+ ions per molecule in solution, usually in two steps

ex. H2CO3 (carbonic acid) and H2C2O4 (oxalic acid)

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4
Q

Triprotic Acids

A

Acid that can donate three H+ proton per molecule in a solution one at a time

ex.
Phosphoric acid (H3PO4)
Cotroc acod (H3C6H5O7

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5
Q

Polyprotic acids

A

Any acid that can donate more than 1 H+ and includes all diprotic and polyprotic ions

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6
Q

Strong acids

A

HCl
HBr
HI
HNO3
H2SO4
HClO4

Hi, HI, BRing NO SOda CLOse

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7
Q

How to name binary acids (acids that consist of two elements H and a nonmetal)

A
  • Anions are either monotomic or non-oxyanions
  • “Hydro” + base name + ic acid

ex. HI - Hydroiodic acid

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8
Q

How to name oxyacids

A
  • Anions are oxyanions (NO3^-, ClO4^-)
    -ate turns to -ic acid
    ex. H2CO3 = Carbonic acid
  • site turns to -ous acid
    H2SO3 = Sulfurous acid
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9
Q

Base

A

Species that is H+ acceptor

Arrhenius definition: A base is a compound that generates OH (hydroxide) ions when placed in water

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10
Q

Strong bases

A

Compounds that release strong OH- ions in a solution and are soluble in water

Group 1 cations
LiOH
NaOH
KOH
RbOH
CsOH

Ca(OH)2
Sr(OH)2
Ba(OH)2

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11
Q

What is the difference between strong and weak acids

A

The strong acids due to completely ionizing, due to every strong acid molecule donating their H+ ion. Weak acids do ionize only partially and leaves unionized molecules in the reaction.

As result there is an equilibrium where the reactions are reversible.

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12
Q

Difference between strong and weak bases

A

Strong bases fully dissociate which means they fully release all OH- ions when dissolved resulting in a high OH concentration

On the other hand weak bases dissociate partially which means only some molecules release OH, leaving a lower OH concentration

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13
Q

Spectator ions

A

Ions that do not change during a reaction

Identified when they are found on both sides of a full ionic equation

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14
Q

How do you identify spectator ions and precipitates based on the solubility rules

A

You can identify precipitates by identifying ions that are exceptions and insoluble in water

You can identify spectator ions by identifying ions are soluble

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15
Q

Weak acids

A

HF
HNO2
HClO
HCN
HC2H3O2
NH4+ (Ammonium)

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16
Q

Weak bases

A

NaF
NaNO2
KClO
KCN
NaC2H3O2 (Sodium acetate)
NH3 (Ammonia)

17
Q

What is pH

A

Scale that measures acidity or basicity of a solution, indicating the concentration of H+ in a solution

Ranges from 0-14 with lower values indicating higher acidity and higher values indicating greater basicity

18
Q

What is the pH of acidic solutions

A

pH < 7 (High H+, low OH-

19
Q

What is the pH of neutral solutions

A

pH = 7 (like pure water, where H+ = OH-)

20
Q

What is the pH of basic solution

A

pH > 7 (low H+, high OH-)

21
Q

Conjugate Acid-Base Pairs

A

The conjugate of an acid is the base that forms when the acid loses a proton (H⁺).

Conversely, the conjugate of a base is the acid that forms when the base gains a proton.

22
Q

For Acids (Finding the Conjugate Base):

A

When an acid donates a proton (H⁺), it turns into its conjugate base.

To find the conjugate base of an acid, remove one H⁺ from the acid formula.

Example: For the acid HCl, if it donates an H⁺, it becomes Cl⁻, which is the conjugate base of HCl.

Conjugate bases have the ability to accept the the H+ back thus it is a base

23
Q

For Bases (Finding the Conjugate Acid)

A

When a base accepts a proton (H⁺), it turns into its conjugate acid.

To find the conjugate acid of a base, add one H⁺ to the base formula.

Example: For the base NH₃ (ammonia), if it gains an H⁺, it becomes NH₄⁺ (ammonium), which is the conjugate acid of NH₃.

24
Q

BAAD

A

Bases Accept Acids Recieve

25
Q

Bronsted Lowry definition of acids and bases

A

Acids are H+ donators

Bases are H+ acceptors

26
Q

Lewis acid definition

A

An electron pair acceptor

27
Q

Lewis base definition

A

An electron base donor

28
Q

What is the net ionic equation and what does it tell us?

A

Simplified version of a chemical reaction that shows the species that participate in the chemical reaction by removing the spectator ions

In acid-base reactions it shows the transfer of H+ or OH ions

In precipitations reactions: It shows only the ions that form an insoluble compound which is the preciptate

29
Q

What is a precipitation reaction?

A

An insoluble ionic compound that forms upon mixing two aqueous solutions of ionic compounds

To get, swap the ions so the cation from one compound partners with the anion from the other compound

Predict precipitates using the solubility rules

30
Q

How do you write complete ionic equations

A

Write balanced molecular equation
- Use correct chemical formulas
- Determine states of compounds based on wording (species dissolved in water are (aq)) and precipitates that form are (s) and solubility rules

Write complete ionic equation
- Go species by species and dissociate strong electrolytes present in aqueous solutions
- weak acids and nonelectrolytes do not get separated

Write net ionic equation
- Cancel spectator ions
- Make sure balanced coefficients are expressed in lowest whole number

Dissociate species that a
nonelectrolytes and undissolved solids associated.

31
Q

Unique aspect of Mercury Hg when given in a chemical equation

A

It forms Hg2^2+ to gain stability

32
Q
A