module two: foundations in chemistry Flashcards

1
Q

atoms consist of

A

nucleus - protons, neutrons
electrons - occupied a region outside the nucleus arranged in shells

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2
Q

mass of an electron

A

1/1836th mass of a proton

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3
Q

isotope

A

atoms of the same element with different numbers of neutrons and different masses

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4
Q

relative isotopic mass

A

the mass of an isotope relative to 1/12th of the mass of carbon-12

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5
Q

relative atomic mass

A

the weighted mean mass of an atom relative to 1/12th of the mass of carbon-12

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6
Q

atomic orbital

A

region around the nucleus that can hold up to 2 electrons with opposite spins

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7
Q

shape of s-orbital

A

spherical

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8
Q

shape of p-orbital

A

dumbell

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9
Q

simple molecular elements

A

H2, N2, O2, F2, Cl2, Br2, I2, P4, S8

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10
Q

metallic elements

A

Mg, Fe, Na, Ni

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11
Q

giant covalent elements

A

diamond, graphite (carbon)
Si

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12
Q

simple molecular compounds

A

CO2, CO, NO2, NO, SO2, SO3, NH3, CH4, H2S

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13
Q

giant covalent compounds

A

SiO2

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14
Q

pV = nRT

A

p = pressure (Pa)
V = volume (m^3)
n = number of moles
R = gas constant (8.314)
T = temperature (K)

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15
Q

metal + acid

A

salt + hydrogen

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16
Q

metal oxide + acid

A

salt + water

17
Q

metal carbonate + acid

A

salt + water + carbon dioxide

18
Q

strong acid

A

fully dissociates in water
releases all its hydrogen atoms
e.g. HCl, HNO3

19
Q

weak acid

A

partially dissociates in water
releases a small proportion of its hydrogen atoms
e.g. CH3COOH

20
Q

why do covalent bonds have low melting/boiling points

A

little energy is req. to overcome the weak intermolecular bonds between the separate molecules

21
Q

conductivity in ionic compounds

A

cannot conduct electricity in solid state as ions ar immobile and cannot carry a charge
can conduct electricity when molten or aqueous as ions are free to move and carry a charge

22
Q

why do ionic compounds have high melting/boiling points

A

high temperatures are needed to prove the large amount of energy req. to overcome the strong electrostatic attraction between the ions

23
Q

why do ionic compounds dissolve in water

A

water is polar
polar water molecules break down the lattice and surround each ion in solution

24
Q

shape of:
2 bonding pairs, 0 lone pairs

A

linear
CO2

25
Q

shape of:
3 bonding pairs, 0 lone pairs

A

trigonal planar
BF3

26
Q

shape of:
2 bonding pairs, 1 lone pair

A

non-linear
SO2, NO2

27
Q

shape of:
4 bonding pairs, 0 lone pairs

A

tetrahedral
CH4

28
Q

shape of:
3 bonding pairs, 1 lone pair

A

trigonal pyramid
NH3

29
Q

shape of:
2 bonding pairs, 2 lone pairs

A

non-linear
H2O

30
Q

shape of:
5 bonding pairs, 0 lone pairs

A

trigonal bipyramid
PF5

31
Q

shape of:
3 bonding pairs, 2 lone pairs

A

trigonal planar
ICl3

32
Q

shape of:
6 bonding pairs, 0 lone pairs

A

octahedral
SF6

33
Q

shape of:
5 bonding pairs, 1 lone pair

A

square pyramid
IF5

34
Q

shape of:
4 bonding pairs, 2 lone pairs

A

square planar

35
Q

linear bond angle

A

180°

36
Q

how can the atom economy of a reaction be improved

A

changing a reaction to have fewer waste products
finding a use for the waste products