Module 6: Reactions Flashcards
1
Q
HBr
A
Hydrogen Halide Addition
* Halide goes on most substituted carbon
2
Q
H2SO4 and ROH
A
Acid Catalyzed Hydration
* OR goes on most substituted carbon
3
Q
Hydroboration Oxidation
A
1) BH3, THF
2) H2O2, NaOH
OH goes on least substituted carbon
4
Q
H2 with Pt/Pd/Ni
A
Hydrogenation
* Syn addition of hydrogen
5
Q
Br2 or Cl2
A
Halogenation
* Anti addition of halogens to both carbons
6
Q
Br2 or Cl2, with H2O
A
Halohydrin
* OH goes on most substituted carbon
* Br goes on the other carbon
* Anti addition
7
Q
Syn-Dihydroxylation
A
OsO4 and NMO/ROOH
OsO4 and Na2SO3/H2O or NaHSO3/H2O
KMnO4 and NaOH
8
Q
Anti Dihydroxylation
A
RCO3H and H3O+
9
Q
O3 and DMS
A
Ozonolysis
