Module 6: Acids and Bases Reactions Flashcards
Hydrochloric acid
HCl
Sulphuric acid
H2SO4
Nitric acid
HNO3
Ethanoic/acetic acid
CH3COOH
Carbonic acid
H2CO3
Phosphoric acid
H3PO4
Citric acid
C6H8O7
Ascorbic acid (vitamin c)
C8H8O6
Sodium hydroxide
NaOH
Ammonia
NH3
Calcium hydroxide
Ca(OH)2
Magnesium hydroxide
Mg(OH)2
Sodium carbonate
Na2CO3
How do you know if something is an acid?
It has a H+
How do you know if something is a base?
It has OH- or O2-
What are the 5 properties of acids?
- Sour taste
- Sting or burn the skin
- Are electrolytes
- Turn litmus paper red
- PH less than 7
What are the 5 properties of bases?
- Bitter taste
- Soapy or caustic feel
- Are electrolytes
- Turn litmus paper blue
- PH greater than 7
What are monoprotic acids?
Acids capable of donating one proton only
What are diprotic acids?
Acids capable of donating two protons
What are the 3 strong acids that need to be memorised?
HCl, H2SO4, HNO3
What are weak acids?
All other acids which aren’t HCl, H2SO4 or HNO3
What are strong bases?
Any which have hydroxides in them
What are weak bases?
Any which don’t have hydroxides in them
What type of arrow is used when there is a strong acid or base in a reaction?
→
What type of arrow is used if both the acid and the base are weak?
⇌
Do acids lose or gain a proton to form its conjugate base?
Lose a proton
Do bases lose or gain a proton to form its conjugate acid?
Gain a proton
What is the acid metal hydroxide word equation?
Acid + Metal Hydroxide → Salt + Water
What is the acid metal word equation?
Acid + Metal → Salt + Hydrogen
What is the acid and metal carbonate word equation?
Acid + Metal Carbonate → Salt + CO2 + Water
How did Boyle describe acids and bases?
Described acids and bases by there property
What did Boyle notice about acids and bases?
Bases could reverse colour change of indicators mixed with acids
What did Lavoisier conclude about acids?
Acids contain oxygen
Why wasn’t Lavoisier’s conclusion that acids contain oxygen correct?
HCl and HCN are also acids
What did Davy conclude about about acids?
All known acids contain hydrogen
What did Davy conclude about bases?
Metal compounds with oxygen are bases
What is an Arrhenius acid?
A molecule that contains hydrogen and can produce H+ ions in water
What is an Arrhenius base?
A molecule that dissociates in water to produce OH-
What did Arrhenius suggest about mixing bases and acids?
That they will produce water
What were the four main limitations of Arrhenius’ idea?
- Could not explain NH3 which has no OH- but is a base
- Could only be applied to aqueous solutions
- Did not explain strength of acids and bases
- Could not explain why some reactions did not form neutral solutions
What is a Bronsted - Lowry acid?
A molecule which is a proton (H+) donor
What is a Bronsted - Lowry base?
A molecule which is a proton (H+) acceptor
What was an advantage of the Bronsted - Lowry theory?
Reactions were no longer limited to aqueous solutions
What were four disadvantages of the Bronsted - Lowry theory?
- A proton that can be transferd must be present for a substance to be an acid or a base
- Model requires a solvent
- Could not explain reaction where no protons are involved
- Could not explain reactions between acidic oxides and basic oxides
What is a Lewis acid?
A molecule that is an electron pair receptor
What is a Lewis base?
A molecule that is an electron pair donor
What were two advantages of the Lewis theory?
- Broader definition to explain more acid and base reactions
Does not require a proton or a solvent
Do acids lose or gain a proton to form a conjugate base?
Lose a H+
Do bases lose or gain a proton to form a conjugate acid?
Gain a H+
What is an amphiprotic substance?
A substance that can either donate or accept protons
What are two examples of amphiprotic substances?
H2O
H2PO4 -
What is a monoprotic acid?
Can only donate one proton
What is a diprotic acid?
Can donate two protons
What is a triprotic acid?
Can donate three protons
What is a polyprotic acid?
Can donate more than one proton
What makes an acid strong?
Readily dissociates in water and donate protons to form hydronium
What is ionisation?
When a free H+ combines with water to form H3O+
What makes an acid weak?
Does not dissociate readily and reacts only partially with water
What makes a base strong?
O2 or OH- readily dissociate in water to make hydroxide ions which can accept protons
What makes a base weak?
Only have a small amount of molecules that have accepted a proton to form ions
How is the strength of a base or acid impact the conjugate base or acid?
The stronger the acid or base the weaker the conjugate base or acid will be
What does strength of an acid/base relate to?
Relates to its ability to dissociate
What does concentration of an acid/base show?
The number of mol/L
What does Kw stand for?
Ionic product constant of water
What can change the Kw?
Slightly changes with temperature or pressure
What is the Kw at normal (25C) of H3O+?
1 x 10^-7 mol/L
What is the Kw at normal (25C) of OH-?
1 x 10^-7 mol/L
What is the Kw of water at normal (25C)?
1 x 10^-14 mol/L
What is the pH scale?
Is a measure of acidity related to the concentration of hyrdonium ions
What are the formulas for pH and pOH?
pH = -log[H3O+]
pOH = -log[OH-]
What are the formulas to find the concentration of H3O+ and OH- from pH and pOH?
[H3O+] = 10^-pH
[OH-] = 10^-pOH
What does pH + pOH = at normal (25C)
14
What is a standard solution?
A solution with an accuratly known concentration
What is the standard solution called in a titration?
Titrant
How is a standard solution made?
By dissolving a primary standard in a known volume of water
What are 7 characteristics of a primary standard?
- Is a solid
- Easily obtained in pure form
- Stable and easy to store
- Has a high molar mass
- Has high solubility in water
- Should react instantaneously
- Should be inexpensive
What is a titration?
A method to determine the concentration of an unknown solution
What is the analyte?
Is the solution of unknown concentration
What is the analyte usually put in?
A conical flask
What is the titrant usually put in?
A burette
What is the titre?
The minimum quantity of a solution required to complete a titration
What is an aliquot?
A small sample of analyte usually 25mL
What is the endpoint of a titration?
The point at which the indicator changes colour
What should the burette be rinsed with?
With the titrant
What should the pipette be rinsed with?
With the analyte
What should the conical flask be rinsed with?
With distilled water
What should the volumetric flask be rinsed with?
With distilled water
What is the chemical representation of the indicator in a chemical equation?
HIn
What is the pH of a strong acid + strong base?
7
What is the pH of a weak acid + weak base?
7
What is the pH of a strong acid + weak base?
pH < 7
What is the pH of a weak acid + strong base?
pH > 7
What are the three indicators usually used?
Methyl orange
Bromothymol blue
Phenolphthalein
What is the pH colour change range of methyl orange?
3.2 - 4.4
What colour is methyl orange in acid, base and neutral?
Acid: Red
Neutral: Orange
Base: Yellow
What is the pH colour change range of bromothymol blue?
6.0 - 7.6
What colour is bromothymol blue in acid, base and neutral?
Acid: Yellow
Neutral: Green
Base: Blue
What is the pH colour change range of phenolphthalein?
8.3 - 10.0
What colour is phenolphthalein in acid, base and neutral?
Acid: Colourless
Neutral: Light pink
Base: Pink
How does pKa influence PH?
The lower the pKa the lower the PH
What does pKa determine?
The strength of an acid
How is pKa calculated?
-log Ka
How do you calculate Ka from a known pH?
Use a rice table and make the change x and then calculate [H3O+] using the given pH
What is the formula for Ka?
PORK but only with aqueous solution
What happens to the pH when an acid is diluted?
pH increases
What happens to the pH when a base is diluted?
pH decreases
What determines the pH of a buffer solution?
Determined by the pKa of the acid and the relative concentration of the acid and its conjugate base
What flask is used when creating a standard solution?
Volumetric flask
How do you identify conjugate acid/base pairs?
There should only be a difference of H+
How do Aboriginal and Torres Strait Islander Peoples use their knowledge of acids and bases?
They use it for both medicinal and nutritional purposes
What is an example of how Aboriginal and Torres Strait Islanders used their knowledge of acids and bases for nutritional purposes?
They ate Quandong a plant that contains high levels of nutritional vitamin C
What is an example of how Aboriginal and Torres Strait Islanders used their knowledge of acids and bases for medicinal purposes?
They used clays which are alkaline to treat stomach issues as basic clays would neutralise the stomach acid
What is the equivalent point?
When the reaction has reached a specific stoichiometric ratio of reactants. The number of H+ is equal to the number of OH-