Module 4.5 - Quantum Physics Flashcards
What is h in E=hc/wavelength
Planck’s constant
What is c in E=hc/wavelength
Speed of light in a vacuum
3 x 10^8 m/s^-1
How to calculate the photon energy if the frequency of the radiation is known
E=hf
How to calculate the photon energy if the wavelength of the radiation is known
E=hc/wavelength
Define electronvolt
The kinetic energy gained by an electron when it is accelerated through a potential difference of 1 volt
Formula to calculate the energy gained by an electron
Energy = charge x potential difference
E=QV
What is the photoelectric effect?
When EM radiation of a particular frequency is shone on the surface of a metal and electrons are emitted from its surface
Parts of the gold-leaf electroscope
Thin gold leaf is attached to a brass stem
Metal cap on top of the stem
What happens when demonstrating the photoelectric effect with the gold-leaf electroscope?
Metal plate (usually zinc) is placed on metal cap and then charged negatively by touching it with a negatively charged polythene rod or by electrostatic induction. Metal stem and gold leaf will become negatively/positively charged so the stem and leaf repel each other.
When would the gold leaf move (i.e. with visible or UV light) and what does this show?
When UV light is shone on a negatively charged zinc plate the leaf falls.
Shows that the metal plate loses its negative charge through emission of electrons, which are repelled by the negative charge on the electroscope. The discharge of the electroscope cannot be caused by ions in the air as it is in a sealed vacuum.
When will electrons be emitted from the surface of a metal?
Only if the incident radiation is above the threshold frequency.
Emission starts the instant the surface starts to be irradiated, proving incident radiation exceeds threshold frequency.
Explanation of the photoelectric effect
Einstein suggested in 1905 that incident radiation wasn’t behaving as a wave but as packets of energy with fixed energy values depending on the light frequency (photons).
What is the work function of a metal?
The minimum energy required to release an electron from the surface.
What is hf in Einstein’s photoelectric equation?
Planck’s constant x photon energy of an incident photon
Why can’t the photoelectric effect be explained using a wave model?
In the wave model, the energy of a wave depends on its amplitude (intensity) not frequency.