Module 4.3 - Quantum Physics ✓ Flashcards
State plank’s equation
E = hf E = hc/l
What were Einstein’s ideas about EM Waves?
He believed EM waves can only exist in discrete packets called photons. Photons act as a particle and will either transfer ALL or NONE of their energy in an interaction
Define the electron-volt?
An electron-volt is the kinetic energy gained by an electron when it is accelerated through a potential difference of 1 volt
How many joules in an eV?
1 eV = 1.6*10^-19 J
Why can threshold voltage be used to find plank’s constant?
1) Current will only pass through an LED if a threshold voltage is placed across it.
2) This is the voltage needed to give the electrons the same energy as the photon emitted by the LED. All the electron’s KE after it is accelerated through the p.d. is transferred into a photon
3) You can use h = ((eV)*l)/c to estimate planck’s constant (comes from E = hc/l)
How does a gold leaf electroscope behave before and after light is shone on it’s plate?
The electroscope plate is initially negatively charged so the gold leaf is repelled. When the plate is exposed to UV light, the photoelectric effect causes it’s free electrons to be ejected, making it loose negative charge and the gold leaf to be repelled less.
What are the three conclusions gained form the gold leaf electroscope experiment?
1 - For a given metal no electrons are emitted if the radiation has a frequency below a certain value
2 - The photoelectrons are emitted with a range of kinetic energies from 0 to some maximum value. Increasing frequency increases this maximum value but intensity does not.
3 - The number of photoelectrons emitted per second is proportional to the intensity of radiation
what does wave theory predict should happen when UV light is shone on a charged plate (photoelectric effect)?
1) For a particular f of light, the energy carried should be proportional to the intensity of the beam
2) The energy carried would be spread evenly over the wavefront
3) Each free electron on the metal surface would gain a bit of energy from each incoming wave
4) Gradually, each electron would gain enough energy to leave the metal
Why does wave theory not explain threshold frequency and the behaviour of increasing intensity?
- The electrons should be emitted eventually no matter the frequency so threshold f does not make sense
- Higher intensity, more energy transferred to each electron, so KE should increase with intensity not just frequency
How does the photon model of light explain the photoelectric effect?
1) When light hits the surface of the metal, it is bombarded by photons
2) If a free electron absorbs one of these photons, it will gain energy equal to hf. If this is enough energy to break the bonds holding it to the metal it will be emitted form the surface
How does the photon model explain threshold frequency?
If the energy gained by an electron from a photon is greater than the work function, the electron is emitted. But if it isn’t the metal will heat up but no electrons be emitted. Intensity does not matter as each photon has a one on one interaction with an electron, more photons with not enough energy won’t help.
What is the photoelectric effect equation?
hf = work function + KEmax
How does the photon model explain maximum kinetic energy?
1) The energy transferred to an electron is hf
2) The KE it will have when leaving the metal will be hf - the energy lost to breaking the bonds holding it there (multiple ways to do this so range of KEs)
3) The minimum energy an electron can loose escaping is the work function so the maximum KE is hf - wf
4) Each electron can only absorb one photon at a time, so increasing the intensity just means more electrons emitted per second rather than each electron having more energy
What was Louis De Broglie’s suggestion?
‘if wave-like light showed particle properties then particles must show wave like properties’
State the De Broglie equation
l = h/p
l > wavelength
h > plank’s constant
p > momentum