Module 3.1.2 - Group 2 Flashcards

1
Q

What is another name for group 2 elements?

A

Alkaline earth metals (all form hydroxides that are alkaline)

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2
Q

What is the electron configuration for group 2 elements?

A

All end in (shell no.)s2

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3
Q

What block elements are group 2 elements and why?

A

They are s-block elements
- their highest energy orbital occupies an s orbital

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4
Q

What structure do group 2 elements have?

A

giant, metallic structure

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5
Q

Why are group 2 elements good electrical conductors?

A

Have mobile delocalised electrons, which can move and carry charge

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6
Q

Why do group 2 elements have a high melting and boiling point?

A
  • a lot of heat energy is required to break the strong metallic bonds
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7
Q

What happens when a group 2 element reacts?

A

A di-positive ion is formed, as the atom loses two electrons

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8
Q

What do group 2 elements undergo?

A

Oxidation

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9
Q

What happens to the atomic radii as you go down group 2 elements?

A

The atomic radii increases down group 2..
- there are more shells, more shielding effect by inner shell electrons
- increased distance of outer shell electron and increased shielding effect far outweigh the increase in nuclear charge
- nuclear attraction decreases on the outer shell electrons down group 2, so atomic radii increases

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10
Q

What happens to first ionisation energy as you go down group 2 elements?

A

First Ionisation energy decreases down group 2 as…
- atomic radius increases
- there are more shells, more shielding effect by inner shell electrons
- increased distance of outer shell electrons from nucleus and increased shielding effect far outweigh the increase in nuclear charge
- nuclear attraction on outer shell electron decreases
- less energy therefore needed to remove an electron from the outer shell of the atom

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11
Q

What happens to reactivity of group 2 elements as you go down?

A

Reactivity as you go down increases as..
- atomic radius increases
- there are more shells, more shielding effect by inner shell electrons
- increased distance of outer shell electrons from nucleus and increased shielding effect far outweigh the increase in nuclear charge
- weaker nuclear attraction on outer shell electrons
- ionisation energy decreases
- less energy is needed to remove 2 electrons from the outer shell of group 2 atom, hence reactivity increases

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12
Q

What happens in group 2 elements with oxygen?

A
  • react vigorously with oxygen to produce an oxide (with ionic bonding)
  • can be burned in air or an atmosphere of pure oxygen
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13
Q

What does a group 2 element and oxygen produce?

A

[Group 2] metal oxide (solid)
redox

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14
Q

What can identify the group 2 element of the metal oxide?

A

The colour of the flame in which the metal oxide is produced in

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15
Q

What is produce when group 2 elements reacts with water

A
  • redox reaction
  • react with cold water (room temperature)

[Group 2] Metal hydroxide (aq) + Hydrogen gas

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16
Q

What are metal hydroxides?

A

Weak bases (pH 10-12)

17
Q

What is seen when group 2 elements react with water?

A
  • solid disappears (dissolves)
  • Bubbles of gas (fizzing - H2 evolved)
18
Q

What happens down group 2 when reacting with water?

A

They react more vigorously down the group

19
Q

What is the reaction between steam and magnesium?

A

Mg (s) + H2O (g) -> MgO(s) + H2(g)

20
Q

What is formed when a group 2 element reacts with an acid?

A

[Group 2] Metal salt (aq) + hydrogen gas , redox

21
Q

What is formed when group 2 oxides react with water?

A
  • an alkaline solution of the metal hydroxide, not redox

metal oxide + water -> metal hydroxide

22
Q

What is formed when group 2 hydroxides react with water?

A
  • Group 2 hydroxides dissolve in water to form alkaline solutions
  • Dissolve into its ions (M 2+, 2OH -)
23
Q

What happens to the solubility of metal hydroxides down group 2?

A

Solubility of group 2 metal hydroxides increases down the group

24
Q

What happens to alkalinity of group 2 hydroxides down the group?

A

Increases down the group

25
Q

What happens to solubility of group 2 sulfates down the group?

A

Decreases

26
Q

How is magnesium hydroxide used industrially?

A
  • Used in indigestion tablets as an antacid
  • Neutralises excess stomach acid safely
27
Q

How is calcium hydroxide used industrially?

A
  • Used in agriculture to neutralise acid soil
  • reacts with acid substances in the soil
28
Q

How is barium sulfate used in industry?

A
  • Used in medicinal purposes for visualising X-rays
  • insoluble in solution, does not release toxic barium ions into bloodstream
29
Q

What is thermal decomposition?

A

The breaking up of a chemical substance with/by heat into at least two chemical substances

30
Q

What are group 2 carbonates decomposed by heat into?

A

Solid metal oxide + Carbon dioxide gas

31
Q

Why do group 2 carbonates become more difficult to decompose with heat as you more down the group?

A

The thermal stability of group 2 carbonates increases down the group