Module 3 Lecture 2 Flashcards

1
Q

Are redox equations equillibrium?

A

No, they do not go in the reverse direction

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2
Q

What must exist if there is an electron transfer?

A

A potential difference

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3
Q

What are the units of potential difference?

A

V or JC-1 = energy per unit charge

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4
Q

What does the potential difference depend on?

A

How big the difference is between the low potential difference and the high potential difference

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5
Q

What does the electrons travel on between the two solutions?

A

A wire

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6
Q

What occurs at the cathode?

A

Reduction

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7
Q

What occurs at the anode?

A

Oxidation

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8
Q

What is the salt bridge used for?

A

Adds anions and cations to compensate for the change in charge in the solution caused by the electron transfer

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9
Q

What represents the salt bridge in a cell diagram?

A

ll

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10
Q

What seperates different states in a cell diagram?

A

l

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11
Q

What is always on the outside of a cell diagram?

A

The species that is attached to the wire

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12
Q

What is standard concentration?

A

1molL-1

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13
Q

If the potentiometer shows a positive value where are the electrons going and what is occurring there?

A

The electrons are going to the right and reduction is occurring

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14
Q

If the poteniometer shows a negative value where are electrons going and what is occurring there?

A

The electrons are going to the left and reduction is occurring there

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15
Q

What does the E^o cell measure?

A

The difference between how much each side wants to gain electrons

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16
Q

What are Erhs and Elhs?

A

The standard reduction potentials for each of the half cells

17
Q

How do you identify the cathode and the anode?

A

The sign of the Ecell

18
Q

Are reduction potentials absolute or relative?

A

Relative

19
Q

How are the reduction potentials worked out?

A

Using a Standard Hydrogen Electrode (SHE)

20
Q

Why can we use SHE’s?

A

Because the E^o of it’s redox couple is zero so it acts as a reference point and gives values and signs to other electrodes

21
Q

What is the oxidant of the spontaneous reaction?

A

Will be the one with this more positive value of E^o