MODULE ... Flashcards

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1
Q

If a system at equilibrium is subjected to a change in conditions that disturb the equilibrium system, the system will proceed to a new equilibrium state in such a direction to partially offset the change in condition.

A

LE CHATELIER’S PRINCIPLE

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2
Q

Le Chatelier’s Principle implies to

A

minimize the stress in response to the change in the system

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3
Q

REMEMBER:

PV = nRT

where
n = number of moles
R = constant
T = temperature

A
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4
Q

Relationship of Pressure to Volume

A

Inversely proportional

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5
Q

IN A CLOSED CONDITION

A

THE MATTER CAN’T ESCAPE.
THE ENERGY CAN ESCAPE.

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6
Q

no change in volume:
_________ effect in inert gas

A

NO EFFECT IN INERT GAS

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7
Q

Change in volume: ______________ NUMBER OF PARTICLES

A

LOWER THE NUMBER OF PARTICLES

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8
Q

EXOTHERMIC

A

release heat

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9
Q

ENDOTHERMIC

A

absorb heat

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10
Q

It speeds up the backward and forward reaction

A

CATALYST

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11
Q

Equilibrium constant

A

Keq = [D]^d [C]^c
______________
[A]^a [B]^b

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12
Q

Characteristics of K

A
  1. REACTION SPECIFIC
  2. CATALYST
  3. FACTORS (concentration; pressure; inert gas; temperature; catalyst)
  4. RELATED TO THE GIBBS FREE ENERGY
    ΔG = -RTlnKeq
  5. Keq changes with Temperature
  6. Krev= 1/ Keq
  7. IF THE STOICH IS CHANGED, THE K CHANGES IN THE FF:
    A+B = C Keq
    3A + 3B = 3C 3 Keq
  8. IF REACTION PROCEEDS IN A STEPWISE MANNER
  9. SIMULATANEOUS REACTION
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