Midterm 2 Flashcards
Salinity
- total quantity of dissolved inorganic solids in water
- ocean’s salinity varies from 33-37‰ (33-37 parts per thousand)
- river water salinity is 0.5 ‰ (0.5 ppt) or less
Turbidity
how much sunlight gets through water column
the process by which water dissolves substances is called
hydration?
Oxidation state of element is controlled by what environmental factors?
water pH and redox potential
water pH
- hydrogen ion concentration
- acidic, neutral, or alkaline
- measured as negative ten-base logarithm
- pH = – log10 [H+]
- One unit pH change = 10-fold change in (H) ion concentration
- pH for surface water ranges from 4 to 9
TDS
total dissolved solids
- sum of all dissolved solutes plus silica SiO2 in water
- in rainwater <20 mg/L
- in rivers 50 - 1000 mg/L
- “Mineral water” > 250 mg/L
oxidation
increase in oxidation state (gain of oxygen, loss of hydrogen, and loss of electrons)
reduction
loss of oxygen, gain of hydrogen, gain of electrons (oxidation number is reduced)
redox potential
- Indicates degree to which substance can oxidize or reduce another substance
- positive ORP reading indicates that substance is oxidizing agent
- negative ORP reading indicates that substance is reducing agent
Diurnal fluctuations in dissolved oxygen:
- Day-time photosynthesis removes CO2 and increases amount of dissolved O2 in water
- However, warmer day-time temperatures decrease amount of dissolved O2 (same in summer)
Seasonal fluctuations of dissolved oxygen
- In summer, base cations (Ca, Mg) prevail; higher alkalinity
- Groundwater dominates stream flow
- In winter, more acidic soil water and surface runoff dominate
chemical weathering
- Weathering – mechanical disintegration
and/or chemical decomposition at the lithosphere-atmosphere boundary - Chemical weathering: 80% of all dissolved matter
- Granite and basalt – the most common igneous rocks containing various silicate minerals
- Low susceptibility to weathering
- TDS in catchments draining sedimentary rocks are five times greater than in igneous rock catchments
80% of dissolved load in rivers: four solutes
calcium Ca, bicarbonate HCO3, sulfate SO4 and silica SiO2
Relationship between precipitation and evaporation
- In arid and semi-arid climates, solutes become concentrated and start to precipitate
- Calcite CaCO3 and dolomite MgCO3
- As a result, higher concentrations of Na, Cl, and SO4 in the water
Rainwater chemistry
- <20 mg/L of TDS
- Dissolved CO2 produces H ion
o acidity increases (i.e. pH falls below neutral)
Hard water
dissolved cations of Ca and Mg (limestones, dolomites)
- “scum line” in bathtubs and kettles; pipe blockage
Soft water
in silicate rocks (sandstones and igneous rocks)
- Major metal ions are Na, K, Mg, Ca in low concentrations
Fund pollutants
pollutants for which environment has some absorptive capacity (Ex: carbon dioxide)
Stock pollutants
pollutants for which environment has little or no absorptive capacity (ex: non-biodegradable litter, heavy metals)
Point-source pollution
discharged into surface water at specific location through drainage pipe or ditch
- Primary point sources are industries and municipalities
- Point sources are relatively easy to monitor and predict
Non-point-source pollution
runoff that comes from various sources and includes agricultural and urban runoff
- Nonpoint sources are much harder to control due to unpredictability and uncertainty of sources
Eutrophication
- accumulation of nitrogen and phosphorous as a result of agricultural runoff and industrial activities
- results: increase in phytoplankton growth, algal blooms, reduced concentrations of dissolved oxygen, deterioration of drinking water quality
thermal pollution
results from injection of heat into watercourse, usually in form of used industrial water
heavy metals
lead, cadmium, mercury
- bio-accumulate in food chains and become persistent pollutants
acid mine drainage
- outflow of acidic water from metal or coal mines
- occurs when pyrite-bearing rocks (FeS2) exposed to oxygen
- common in abandoned mines (active mines pump out water)
acid rain
- atmospheric deposition of acidic substances, such as SO2 and NO2
- when sulfur is release into atmosphere, it combines w/ moisture in chemical reaction to make acid rain
- acid rains have acidity below pH of 4
- sea water pH = 8
water acidification
high acidity results in increased solubility of heavy metals (Al, Mn, Pb, Cd, Zn, As)
- at pH <5, Al (aluminum) becomes soluble and leaches into aquatic systems from soils
- fish osmoregulation (ability to control flow of water, salts, and gases in and out) is comprised at Al concentrations
Salt water intrusion
saline intrusion b/c of depletion of groundwater reserves in coastal areas
The Water Quality Act of 1965
- established ambient water quality standards for interstate watercourses
- states required to file implementation plans