MIDTERM 01 - Solubility Flashcards
Refers to the ability of a solute to dissolve in a solvent
Solubility
3 solubility parameters/profiles (AKT)
Apparent, Kinetic, Thermodynamic
Refers to solubility observed under experimental conditions (Types of solubility parameters/profiles)
Apparent solubility
Refers to solubility determined by rate of dissolution (Types of solubility parameters/profiles)
Kinetic solubility
Refers to solubility when the system is in equilibrium (Types of solubility parameters/profiles)
Thermodynamic solubility
Refers to how fast a solute dissolves in a solvent (Factors affecting solubility)
Dissolution rate of solute
Generally, a higher temperature results to a higher solubility (Factors affecting solubility)
Temperature
Relationship between temperature and solubility in solids
Directly proportional
Relationship between temperature and solubility in liquids
Directly proportional
Relationship between temperature and solubility in gases
Inversely proportional
Involves salting in and salting out (Factors affecting solubility)
Addition of salt
Results to an increase in solubility by stabilizing ions in solution
Salting in
Results to a decrease in solubility by competing with water molecules
Salting out
The formation of a complex with another compound can enhance solubility by stabilizing the solute in the solution (Factors affecting solubility)
Complex formation
Converting a solute into its salt form often increases solubility due to better dissociation in water (Factors affecting solubility)
Salt formation
Meaning of LUNA
Lipophilic, Unionized, Nonpolar, Absorbed
Meaning of HIPE
Hydrophilic, Ionized, Polar, Excreted
Amorphous solids have higher solubility than crystalline forms because their disordered structure dissolves more readily in a solvent (Factors affecting solubility)
Amorphous form
Very soluble (Parts of solvent used to dissolve 1 part of solute)
<1
Freely soluble (Parts of solvent used to dissolve 1 part of solute)
1-10
Soluble (Parts of solvent used to dissolve 1 part of solute)
10-30
Sparingly soluble (Parts of solvent used to dissolve 1 part of solute)
30-100
Slightly soluble (Parts of solvent used to dissolve 1 part of solute)
100-1000
Very slightly soluble (Parts of solvent used to dissolve 1 part of solute)
1000-10,000
Practically insoluble (Parts of solvent used to dissolve 1 part of solute)
> 10,000
Title of experiment 2
Solubility
Is an oven designed to precisely heat and dry samples at the same time
Memmert oven
Laboratory specification/temperature for Memmert oven
105°C
Place __________ of distilled water into a 250 mL Erlenmeyer flask
20 mL
Introduce a __________ amount of sample to the water and stir
Corn grain
Shake the solution continuously for __________ minutes
15 minutes
Pipette two portions of __________ mL of the filtrate into two separate tared evaporating dishes
5 mL
Set the Memmert oven at 105°C and heat the solutions for __________ hours
1.5 / 1 1/2 hours