Metals and alloys Flashcards
Examples of metals and alloys in dentistry
Amalgam - restorations Cobalt chromium - dentures Stainless steel - braces Gold - restorations Titanium - implants
Metals in amalgams
Ag/Sn/Cu alloy and Hg
Metals in inlays/ onlays
Au alloys, Pd alloys
Metals in crowns
Stainless steel, Au alloys, Pd alloys, Ni/Cr alloys
Metals in bridges
Au allots, Pd alloys, Ni/Cr alloys
Metals in dentures
Co/Cr alloys, stainless steel
Metals in dental impants
Titanium
What is a metal?
A crystalline material held together by metallic bonds (free electrons and cation)
Compare crystal structures
Face centred cubic (packing factor 0.74)
Body centred cubic (packing factor 0.6)
Metal microstructure
(Usually) polycrystalline structure consisting of grains and grain boundaries
- Must polish and etch to see this, creates contrast
- Liquid: nuclei of crystallisation
- Solid: grain and grain boundaries (frozen)
Which metal are used in their pure form in dentistry
Gold, platinum and titanium
Types of alloys
- Substitutional solid solutions
- Interstitial solid solutions
- Intermetallic compounds
Subsitutional solid solutions
- diff atoms have same valency with same crystal structure
- atomic size within 15%
e. g. Au and Cu
Interstitial solid solutions
- solute atom ≤ solvent atom
- solute atoms occupy space between solvent atoms
- distortion of lattice occurs to accomodate extra atoms
- e.g. Fe and C
Intermetallic compounds
- Formed when 2 or more metals combine with discrete composition/ stochiometric ratio
- e.g. amalgam: contains silver/tin compound (Ag3Sn) and copper/ tin compound (Cu6Sn5)