Metals Flashcards

1
Q

Reaction with water: Mg Al Zn Fe

A

Very slow reaction with cold water. React when heated in steam producing an insoluble metal oxide and hydrogen

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2
Q

Reaction with water: Cu Ag Au

A

No reaction with water or steam

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3
Q

How do you find the reactivity of cobalt

A

Get 5 test tubes and add cobalt nitrate
Then add magnesium, zinc, silver, iron and copper
If the metal is more reactive than cobalt then the element will begin to form on the surface of the metal
If no reaction occurs the metal is less reactive

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4
Q

What’s an ore

A

A mineral containing a metal compound from which the metal can be economically extracted

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5
Q

What are the three stages involved in extracting metals

A

Mining the metal ore and concentrating it
Conversion of the metal ore into the metal
Purification of the metal

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6
Q

What is aluminium extracted from

A

Bauxite (impure aluminium oxide)

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7
Q

Give four metals that cannot be extracted from their ore by reduction with carbon or carbon monoxide

A

Potassium sodium lithium and magnesium

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8
Q

How are potassium sodium lithium and magnesium extracted

A

By passing an electric current through a molten compound, which splits it up into the original elements (electrolysis)

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9
Q

What is the main ore of iron

A

Haematite (iron (|||) oxide)

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10
Q

How is iron extracted from its ore

A

The ore is grown up
It is mixed with limestone and coke
This is added to the top of the blast furnace
Air (preheated to 600 degrees Celsius) is injected into the furnace through pipes
Molten iron is tapped from the lower tap hole (slag is tapped from the higher one)
The process is continuous

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11
Q

Name four substances (raw materials) that go into the blast furnace

A

Iron ore (Fe2O3)
Coke (treated coal)
Limestone (CaCO3)
Air (O2)

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12
Q

Name three substances that come out of a blast furnace

A

Molten iron
Molten slag
Waste gases

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13
Q

What happens at the bottom of a furnace

A

Coke reacts with oxygen in the hot air
C + O2 = CO2
This reaction is exothermic

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14
Q

What does the heat produced during the reaction with coke and oxygen do

A

Decomposes limestone forming calcium oxide and more carbon dioxide
CaCO3 = CaO + CO2

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15
Q

What happens when carbon dioxide works it’s way up the furnace

A

It is reduced to carbon monoxide at about 1500 degrees Celsius by reaction with more coke
CO2 + C = 2CO

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16
Q

What is the main reducing agent in the blast furnace

A

Carbon monoxide, it reduces the haematite to iron at about 600 degrees Celsius and producing carbon dioxide

Fe2O3 + 3CO = 2Fe + 3CO2

17
Q

What is the main purpose of the limestone in a blast furnace

A

To remove impurities. These are mainly silica which, if left in the iron, would make it brittle and so they react and are neutralised at about 900 degrees Celsius by a basic oxide (formed by the thermal decomposition of limestone) to form slag
CaO + SiO2 = CaSiO3

18
Q

Why does the molten slag sit on top of the molten iron

A

It is less dense, and it is to prevent the reoxidation of the iron by preheated air

19
Q

Why is the iron from the blast furnace not very useful

A

It has a high concentration of carbon impurities and is very brittle

20
Q

Why is pure iron not useful

A

It is very soft and stretches easily and is less brittle than cast iron; it also rusts easily

21
Q

What is an alloy

A

A mixture of metals or of a metal and carbon

22
Q

What two substances are needed for iron to rust

A

Water and oxygen (iron (|||) oxide)

23
Q

Rust prevention methods

A

Paint (cars)
Grease (bicycle chains)
Plastic (chain link fence)

24
Q

What is sacrificial protection

A

When a block of metal more reactive than iron (eg zinc) is added to the iron. So it will corrode before the iron does

25
Q

What is galvanising

A

When iron is protected from rusting by dipping the iron into molten zinc so that the iron is completely coated. It is used for dustbins and buckets

26
Q

Where are transition metals in the periodic table

A

The central block

27
Q

Mild steel

A

Malleable

Used in car bodies chains and pylons

28
Q

Hard steel

A

Hard and strong

Used in chisels files saws and razor blades

29
Q

Stainless steel

A

Does not rust

Used in cutlery kitchen sinks sculptures and surgical instruments

30
Q

Titanium steel

A

Low density high strength does not rust

Used in the edges of high speed cutting tools, armour plating, darts viola strings and golf clubs

31
Q

Equation for the reaction at the cathode

A

3+ _

Al + 3e = Al

32
Q

Equation for reaction at anode

A

2- + -

2O = O2 + 4e

33
Q

What are the anode and cathode made of

A

Graphite

34
Q

Where is the cathode in an electrolytic cell

A

At the bottom, below the molten aluminium

35
Q

Why does the anode need frequent replacement

A

At 1000 degrees Celsius the graphite anodes burn away in the oxygen to give carbon dioxide

36
Q

Why is cryolite added in the electrolyte

A

To reduce the operating temperature of aluminium from 2000-800 degrees Celsius and when it is molten it acts as a solvent for the alumina

37
Q

What kind of melting points and boiling points do metals have

A

High

38
Q

What kind of melting and boiling points to non metal as have

A

Low unless they have a giant covalent lattice structure

39
Q

reaction with water: K Na Li Ca

A

React with cold water giving soluble metal hydroxide and hydrogen