Metal Flashcards
Main metals used for food packaging:
Aluminum
Iron
Mineral sources of iron (ores):
hematite
magnetite (highest %)
limonite
siderite
Ore source for aluminum:
Bauxite
True/False: there is greater amounts of iron than aluminum in the Earth’s crust
False
Al is 8.1%, Fe is 5%
Iron is usually transformed into ____ for food packaging
steel
the raw materials for steel production: (3)
C (Coal)
CaCO3 (limestone)
Fe2O3 (iron ore)
What is slag? how is it made
CaSiO3
made from CaO (from limestone) + SiO2
in making iron into steel, you need to reduce __, ___, ___, ___, and add ___, ___, ___
reduce Si, C, P, S
Add Mn, Ni, Cr
An increase in % of Carbon in steel will have what effect on the properties?
increase in hardness, tensile strength
decrease in ductility and welding properties
What can be added to steel to increase corrosion and abrasion resistance?
Cr
What steel component will increases hardness/tensile strength, especially at high temperatures?
Mo
What is the effect of increasing Mn in steel?
increase strength and hardness
What is the effect of increasing P in steel?
increase strength and hardness
decrease ductility
What is ductility?
ability to be stretched into a wire
What is the effect of increasing Ni and Cu in steel?
increase toughness, tensile strength, hardness, corrosion resistance
What are common types of steel for food packaging? (4)
Type L (high purity, low P/residual metals) Type MR (higher P/residual metals) Type D (Low C, high S, stabilized) Type Ni (Added Ni)
What steel is used for highly corrosive products?
Type L
What steel are drawn and ironed cans made from?
Type D
What is Ni steel used for?
Can ends, aerosol domes
What is Type MR steel used for?
mildly/non corrosive products (low acid)
What is used to describe metal hardness?
temper
the different temper grades:
T1 (46-52) - soft, for deep draws T2 (50-56) - moderate draws, closures T3 (54-63) - shallow draws, gen. purpose T4 (58-64) - bodies/can ends T5 (62-68) - bodies/can ends
What temper grades can be used for can bodies and ends?
T4 or T5
What are types of plating steel?
Electrolytic tinplate (ETP)
Chromium coated steel
Polymer coated steel
What is ETP?
electrolytic tinplate (plated steel) tin-iron alloy later at interface of tin/steel -> gives corrosion resistance
Steps for preparing ETP: (4 steps)
electrolytic process: bathe tin sulfate in sulfuric acid
thermal treatment (260-270C) & rapid quenching
chemical passivation in Na dichromate solution
apply oily lubricant
advantages (5) vs disadvantages (2) of chromium coated steel?
good: spontaneous passivation (thinner), cheaper, better heat resistance, coating adhesion, printing
bad: low abrasion resistance, decrease resistance to corrosion
What is polymer coated steel coated with? What does this achieve?
Polytetrafluoroethylene (PTFE), perfluoroalkoxy alkane (PFA), fluorinated perfluoroethylenepropylene (FEP)
resist abrasion, corrosion, food interactions
For a highly acidic food, what would be a good steel coating?
polymer coating (PTFE, PFA, or FEP)
2 processes needed to convert aluminum ore into aluminum:
- Bayer process
2. Hall heroult process
Requirements of the Hall Heroult process:
cryolite (Na3AIF6)
huge amount of energy needed
The bayer process converts ___ into _____
Bauxite
alumina
Aluminum can be combined with many metals such as _______, to form various ____.
Mn, Si, Fe, Mg, Cu, Cr
alloys