Mechanisms Flashcards

1
Q

Alkane&raquo_space;> halogenoaklane

A

Free-radical substitution

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1
Q

Alkene&raquo_space;> (di) halogenoalkane / alkylhydrogensulfate

A

Electrophilic addition

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2
Q

Halogenoalkane&raquo_space; alcohol/nitrile/amine

A

Nucleophilic substitution

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3
Q

Halogenoalkane&raquo_space;> alkene

A

Elimination

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4
Q

Conditions and reagents for nucleophilic substitution to form an alcohol:

A

Reagents - KOH or NaOH
Conditions - warm and aqueous

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5
Q

Conditions and reagents for nucleophilic substitution to form a nitrile:

A

Reagent - KCN
Conditions - warm and ethanolic

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6
Q

Conditions and reagents for nucleophilic substitution to form an amine:

A

Reagents - excess NH3
Conditions - warm and ethanolic

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7
Q

Conditions and reagents for elimination:

A

Reagents - KOH or NaOH
Conditions - hot and ethanolic

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8
Q

KEY DEFINITION: electrophile

A

An electron pair acceptor

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9
Q

KEY DEFINITION: nucleophile

A

An electron pair donor

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10
Q

What is the role of OH- ions in nucleophilic substitution?

A

Nucleophile (electron pair donor)

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11
Q

What is the role of OH- ions in elimination?

A

Base

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