Measuring pH Flashcards

1
Q

[x] means

A

the concentration of x

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2
Q

what is the equation to show when water molecules undergo self ionisation

A

H2O(l) + H2O(l) ⇌ H3O+(aq) + OH−(aq)

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3
Q

how does water behave when reacting with itself

A

as both a very weak base and very weak acid

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4
Q

Kw

A

ionic product of water

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5
Q

formula to calculate Kw

A

[H3O+][OH-]=1x10^-14 at 25°C

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6
Q

how is the Kw formula justified

A

all aqeuous solutions conatin H3O+ ions and OH- ions and the product of their molar concentrations is always 1x10^-14 at 25°C and therfore if either [H3O+][OH-]increases than the concentration of the other must decrease proportionatley

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7
Q

formula to calculate concentration of H3O+ from known concentration of OH-

A

[H3O+] = 1x10^-14/[OH-]

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8
Q

formula to calculate concentration of OH- from known concentration of H3O+

A

[OH-} = 1x10^-14/[H3O+]

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9
Q

[H3O+][OH-] is known as

A

the ionic product of water

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10
Q

in pure water and neutral solutions [H3O+]

A

10^-7

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11
Q

in pure water and neutral solutions [OH-]

A

10^-7

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12
Q

in acidic solutions [H3O+]

A

[H3O+]>10^-7

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13
Q

in acidic solutions [OH-]

A

[OH-}<10^-7

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14
Q

in basic solutions [H3O+]

A

[H3O+]<10^-7

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15
Q

in basic solutions [OH-]

A

[OH-}>10^-7

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16
Q

how to calculate [H3O+] from known acid concentration

A

if the acid contains 1 hydrogen atom, its [H3O+] is equal to its concentration,if the acid contains 2 hydrogen atoms its [H3O+] is double its concentration

17
Q

how to calculate [OH-] from base

A

if the base contains 1 hydrogen atom, its [OH-] is equal to its concentration,if the base contains 2 hydrogen atoms its [OH-] is double its concentration

18
Q

formula to calculate pH

A

pH=-log10[H3O+]

19
Q

at 25°C, neutral solutions have a pH of

A

7

20
Q

at 25°C, acidic solutions have a pH of

A

less than 7

21
Q

at 25°C, basic solutions have a pH of

A

more than 7

22
Q

a solution of pH 2 has how many more H3O+ ions than a pH of 3

A

ten times the concentration of the H3O+

23
Q

how to calculate the [H3O+] from known pH

A

[H3O+] = 10^-pH

24
Q

pH metres do what

A

provide a specific quantitative measurement of pH

25
Q

how do pH metres work

A

by measuring the difference in electrical potential between two probes due to the concentration of charged particles or ions in the solution

26
Q

what are indicators

A

substances that change colour when they are added to an acidic or basic solution

27
Q

what is universal indicator

A

a mixture of a variety of other indicators that can be used to measure the approximate pH of a solution

28
Q

litmus paperr

A

one of tthe simplest and most common indicatorrs which uses a dye derived from lichens

29
Q

litmus paper in acidic solutions

A

blue litmus paper will turn red

30
Q

littmus paper in basic solutions

A

red litmus paper will turn blue

31
Q

why as indicators less accurate then pH metres

A

indicators only provide a pH range for a given solution

32
Q

accuracy of pH metres

A

highly accurate, usually correct to +-0.01 pH uints and is built into the calibration of the metre

33
Q

why are pH metres more precise

A

because there is no change to the calibration of the instrument between measurements

34
Q

why are indicators less precise

A

the estimated pH of a given solution may differ greatly between multiple trials

35
Q

end point

A

the point at which the indicator changes colour