Measuring pH Flashcards
[x] means
the concentration of x
what is the equation to show when water molecules undergo self ionisation
H2O(l) + H2O(l) ⇌ H3O+(aq) + OH−(aq)
how does water behave when reacting with itself
as both a very weak base and very weak acid
Kw
ionic product of water
formula to calculate Kw
[H3O+][OH-]=1x10^-14 at 25°C
how is the Kw formula justified
all aqeuous solutions conatin H3O+ ions and OH- ions and the product of their molar concentrations is always 1x10^-14 at 25°C and therfore if either [H3O+][OH-]increases than the concentration of the other must decrease proportionatley
formula to calculate concentration of H3O+ from known concentration of OH-
[H3O+] = 1x10^-14/[OH-]
formula to calculate concentration of OH- from known concentration of H3O+
[OH-} = 1x10^-14/[H3O+]
[H3O+][OH-] is known as
the ionic product of water
in pure water and neutral solutions [H3O+]
10^-7
in pure water and neutral solutions [OH-]
10^-7
in acidic solutions [H3O+]
[H3O+]>10^-7
in acidic solutions [OH-]
[OH-}<10^-7
in basic solutions [H3O+]
[H3O+]<10^-7
in basic solutions [OH-]
[OH-}>10^-7