Materials Flashcards
Ceramics (Properties)
Properties: -BRITTLE
-resistant to corrosion/environmental degradation = long lifespan,
- hard, strong in compression:
- high stiffness (Young’s mod)
- high melting temp
- thermally and electrically insulating
- low thermal shock resistance
- resistant to vibrations
good for CIVIL STRUCTURES
Ceramics: What are they?
Compounds of: Metals and non-metals thru ionic bonding, non-metals via COVALENT bonding
Ceramics: common types
Stone
Clay ceramics
Cement
Glass
Stone types
Igneous: volcanic prosses (e.g. Basalt for asphalt and road bases, Granite for masonry)
Metamorphic: High pressure (e.g. slate in roofing, Marble for decoration)
Sedimentary: Deposition (e.g. Limestone for cement, Sandstone for masonry)
Stone properties
Weak in tension, strong in compression, low toughness (brittle)
- easy to chisel/hand carve (masonry)
Usually rough finish
Clay ceramics:
KAOLINITE: plate-like structure: absorbs water well: plastic and slippery (easy to form)
- can have other additives e.g. quartz to reduce shrinkage, alter plasticity, reduce firing temp
Clay firing:
DrDeOV
Drying (>150): evaporation of water between platelets, loss of plasticity
Dehydration: (400-600) Dehydration of kaolinite
Oxidation:(300-700)
Vitrification (>900) Formation of mullite clusters with a glassy matrix: severe shrinkage
Cement (definition, composition and 2 types)
A binding agent made of limestone and clay, good adhesive properties yet weaker than cement and prone to cracking (Romans, not used widely until 19th century)
Alumina, soda and lime are reacted at high temperatures.
Non-hydraulic: set when exposed to air
Hydraulic: set due to a chemical reaction with water (can be used underwater)
setting is EXOTHERMIC
Cement properties
Strong in compression, weak in tension and low toughness. similar to stone with properties by is able to be cast
Cement powder formation
- Limestone and shale mixed together and ground
- Heated in kiln to fuse and form clinker
- ground clinker mixed with gypsum (slows setting time)
4.Reground and mixed
Lime Mortar (and making process)
Non-hydraulic,
- made by mixing limestone and silica, alumina and iron
- Firing at 1000 (LASI)
- adding water makes hydrated/slaked lime
- This mixed with sand is lime mortar: used historically in brick and stone buildings.
Gypsum
Non-hydraulic: when made by hydrating calcium sulphate to form a semi hydrate, it is PLASTER of Paris
- soft, porous, water-soluble
- USES: art and building lining
OR when heating cal. sulf. to form anhydrate: Keene’s cement
- hard, strong, insoluble
- used in exposed surfaces, imitation marble
Pozzolana
Siliceous material used in making Roman Hydraulic cement
- naturally occurring (volcanic)
Made from silica, alumina and iron oxide
- Cement is made with pozzolana, lime and water (heated and ground into powder)
- mixed with water and aggregate to make concrete
Glass (structure and how to make)
AMORPHOUS structure silica: made by adding a network modifier, e.g. soda and lime to quartz-based sand
Glass properties
Transparent due to loose structure, crystallized glasses are TOUGHER but less optical clarity.
Unfavourable to machining due to lack of slip planes: must be done at high temperatures where viscosity is reduced
- brittle, low toughness, weak in tension
Types of Glass modification:
- Chemically: addition of oxides e.g. boron, coloured pigments, modifiers e.g. lead
- Mechanically: lamination with polyvinyl butyl (laminated glass has an interlayer of polymer to prevent penetration, breaks on impact, keep shards intact etc.): CARS
- Heat treatment: soften and releases internal stresses to produce toughened glass: outside cooled, inside cools slower and thus shrinks, leaving the outside in compression.
Types of glass
annealed glass, breaks easily in long, sharp shards: soaked at 470 then cooled slowly
Heat strengthened glass: resistant breakage ~2x stronger
Fully tempered glass: resistant to breakage, ~4x as strong as tempered, shatters in small pieces
lamination with polyvinyl butyl (laminated glass has an interlayer of polymer to prevent penetration, breaks on impact, keep shards intact etc.)
Composites (Defininition)
Consists of two or more materials joined mechanically: creates properties unattainable from the original materials.
Composites classifications:
Natural (timber, some stone)
Fibre-reinforces (fibreglass, carbon fibre and geotextiles)
Particle reinforced (concrete)
Dispersion-strengthened: (precipitation hardened, sintered metals)
Laminated (wood products with metal/plastic laminates)
Concrete composition
Composite of cement, sand, aggregate
Role of aggregate (sand + Water) is to:
- Resist applied loads and abrasion
- Provide a filler for cement to bind
- Reduce volume changes when setting
Role of cement-water paster:
- lubricate concrete mix
- fill voids between aggregate
- strengthen the concrete
Dry concrete mix in a 4:2:1 ration
Concrete MACROSTUCURE
heterogeneous microstructure:
BIG grey: angular coarse aggregate
Small grey: angular fine aggregate
Fine sand particles within cement paste
Concrete characteristics:
Advantages:
- high compressive strength
- moldable
- durable against corrosion and rot
- fire resistance
- heat + noise insulating
- low cost
- can be reinforces
- can be precast or formed on site
Disadvantages:
- heavy
- labour intensive
- slow to set and cure
- can spall, crack or experiences chemical deterioration
- Low toughness and tensile strength
Crack formation and growth
Higher Strain energy = more chance for crack formation (cracks release strain energy which concentrates the bottom of the tip: thus crack growth accelerates with time
- method of brittle failure
Critical Crack length
Once this length is achieved, the crack will continue until failure.
Destructive testing Types:
Compressive: concrete: subjected to testing across different time intervals. Load applied is measure, as well as the way the concrete destructed
Transverse: (bending and shear)
Torsion: (twisting forces e.g. couples)
Tensile: Applying a tensile force until necking and then fracture.
Elastic vs Plastic deformation
Elastic: Metallic bonds stretch but do not break
Plastic: applied force is enough to break metallic bonds: Permanently deform along a slip plane
(NOTE: BCC cells have more slip planes the FCC)
How does Work Hardening work?
Work hardening moves dislocations through the lattice structure, increasing the amount of dislocations and thus making it less ductile more brittle.
How to grain boundaries form?
Through the random nature of cooling, unit cell lattices will grow and then merge to create grain boundaries
3 Non-destructive testing types:
- X-ray testing:
- observe cavities and cracks - Dye penetration test:
- See cracks existing on the surface. Area is prepped by removing surface contaminatnts e.g. oil, then heated. Dye is applied, excess whiped off. A developer is appplied, then cooled. (squeezes out dye from cracks from shrinkage) - Ultrasonic testing:
- similar to x-ray, expect radio waves instead. Waves sent out, reflected to transmiter. (Early waves = cavity)
Slump Test
Measures workability, compacts a sample into a metal cone which is tempered multiple times, before lifting and measuring how far the concrete collapses. The greater the slump, the increased workability. However, collapse = too wet, crumbling = too dry
High slump = narrow or complex structures, low slump = larger structures
Strain energy
The amount of energy stores in a material that has undergone strain (e.g. tensile, compression, torsion, bending)
SE=1/2 stress x strain
Tranverse bend/beam testing
Three or four point loading (^—v—-v—^ vs ^—-v—-^)
measures flexural strength or modulus of rupture
Types of Cast Iron:
- White cast iron
- Grey cast iron
3.Malleable cast iron - Ductile/nodular/spheroidal cast iron
White Cast Iron
Low carbon, <1% silicon (graphite cannot form)
- dendrites of pearlite in a cementite matrix
- Hard, brittle, good castiblility
Grey cast iron
- High carbon, enough silicon to make graphtite
- Graphite flakes (make it prone to fracture) in a pearlite/ferrite mixture
- lower tensile strength, vibration dampening self-lubricating, resistant to corrosion
Malleable cast iron
- High carbon and silicon
- Graphite rosettes in pearliitic/ferritic matrix (made by heat-treating WCI)
- Soft, malleable, ductile, tough, machinable
Ductile/nodular/spheroidal cast iron
Highest carbon and silicon, some magnesium or cerium
- Graphitic spheroids in a pearlitic/ferritic matrix
- Soft, malleable, tough, machinable
Types of Imperfections in lattice structures:
- Point defects
- Dislocations
- Planar imperfections (e.g. grain boundaries)
What is Cast Iron and properties?
2-4% carbon content, usually brittle especially under tension, with high compressive strengths.
- cheap in production
- Good wear resistance and hardness
- Typically manufactured in a mold
Cracking Prevention and fixing for ceramics, metals and polymers
If metallic: welding
- repairs crack, however other microstructural changes weaken material (potential point of stress concentration)
- must be then heat treated
Polymeric materials:
- adhesives, polymer welding (thermoplastic)
Ceramic materials:
- drill a hole to release strain energy buildup
PREVENT: don’t use sharp corners, add interfaces (prevents critical crack length)
Timber composition and types
Consists of cellulose fibers/tracheids, held together in a lignin resin.
Hardwood vs softwood: pored vs non-pored
Timber Properties
High specific strength (strength/weight ratio), reasonable at bending
Good Young’s modulus
Adversely affected by weather, susceptible to attacks by pests. (not long-lasting)
Concrete reinforcement:
Reinforced concrete: Reinforces with steel rods/mesh that takes tensile load.
Pre-stressed reinforced concrete: tensioned beams in concrete, which when released, place in compression
Post-tensioned: wires are pulled thru slab
Spalling and prevention
Steel inside corrodes: expands, cracks concrete: prevented by ensuring correct water ration, vibrate concrete to reduce porosity
Asphalt composition and properties
Good for road surfaces: made with hard aggregate (often slag or basalt) and bitumen as matrix.
Tough, crack-resistant but hard-wearing. Impervious to contamination by oil. Can deal with slight movements in road.
Laminates: what and examples
Varying materials sandwiched together
Plywood:
= timber with grain structure and 90 degree angles.
Laminated veneer lumber (LVL): stronger then timber, less susceptible to shrinkage or warping
Laminated glass: shatter resistant
Bimetallic strips: two metals back to back (thermostats, protection circuits)
Geotextiles: what and properties/uses
Woven polymers (usually polypropylene, polyester or ceramic fibers)
Stabilising road bases (under asphalt, often contaminated by earth underneath): makes layer between base and subsoil
Filters for drainage systems, stop dirt from getting into storm water runoff.
Corrosion: (dry and wet)
Chemical deterioration of a material (‘reverse refinement”)
Dry:
- chemical reactions with gases in furnaces at high temps e.g. steam locomotive boilers, water tubers.
Wet:
- metal is placed in a fluid usually electrolyte.
Wet corrosion types: (uniform and galvanic)
Uniform attack:
- placed in electrolyte, some parts cathodic, some anodic (constantly changing)
Galvanic:
1. corrosion: dissimilar metals placed together, more anodic will corrode.
2.Concentration cells: difference in concentration of electrolyte e.g. trapped water.
3. Stress cells: high residual stress in parts of metal object. (high stress = anodic) e.g. grain boundaries
Oxidisation and reduction
O: loses electrons at anode
R: gains electron at cathode
The more cathodic = more stable e.g. platinum.
Passivity
When a metal forms a protective film from corrosion, e.g. aluminum, titanium, chromium.
Rust
Needs water and oxygen: continually flakes off to expose metal underneath
Protecting against corrosion (5 types)
Painting the steel: provides protective layer
Galvanising: dipping steel into molten zinc: protects from corrosion for far longer. Other products can then be added on top to further this effect.
Cathodic Protection: object made cathode to prevent corrosion
ICCP systems: use a current to reverse standard electrical flow: steel becomes cathode (found in pipelines, long structures, etc)
Sacrificial Anodes:
- using blocks of more anodic metals bolted nearby (steel becomes cathodic): e.g. ship hulls.
Steel Properties
Cost effective, tough, strong in tensile and compression, ease of fabrication, hard, ductilie
- properties are manipulatable
Train environmental factors
Still use a lot of pollution HOWEVER better then individual transport options
- Train lines are use far less land then roadways
4 Testing processes for hardness
Brinell: Hardened steel ball impressed into surface, SA measured.
Vickers: Square pyramid, (V is POINTY) Formula with load and area (better for thin metals)
Rockwell: smaller diamond cone or sphere pressed into surface, DEPTH
Shore Scleroscope: a small striker in a tube: height it rebounds is measured.
4 Types of Steel: (alloys)
Carbon steel
Stainless steel
Alloy steel
Tool steel
Impact tests: what do they measure? 3 Types?
They measure notch toughness (ability for material to absorb shock energy)
Izod: large pendulum raised to give it PE, then struck against the test piece, losing KE and thus not reaching as high. The height reached is recorded. Sample has v shaped notch to promote crack propagation
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Charpy: nv
`n held horizontally, notch away from pendulum.
Hounsfield: Smaller, transportable: uses two pendulums
Process Annealing:
Heating steel with <0.3% C to a temp ~ 550-650. Relieves stress from distorted grains e.g. after cold working, deformation. Cooled in still air. FERRITE UNSTRESSED, PEARLITE STRESSED
Full Annealing
Heat hypo-eutectoid or eutectoid steels to AUSTENITE or 40 degrees above upper critical temperature (UCT). Cooled in furnace. All grains unstressed.
Austenite
FCC structure, only occurs at high temperatures.
Normalising
Heating to austenite region far above UCT. Cooled in still air.
Shorted the annealing, finer grain structure and thus stronger steel.
Spheroidising
Medium to high carbon steels: high cementite = hard to machine
Heating to 650-700, holding it there. Cementite in pearlite makes spheroids: much easier to machine
Steel ranges and properties (low, mild, medium, high, ultra high)
Low carbon: up to 0.15%.
- soft, ductile, malleable
- Sustain cold-working
- Equiaxed ferrite grains, some pearlite
- Rivets, car bodies, chains e.t.c.
Mild: 0.15-0.3%
- “”
- structural steels
Medium: 0.3-0.6%
- Tough, hard, machinable
- small equiaxed ferrite, mostly pearlite
- shafts, axels, gears, etc.
High carbon: 0.6-0.9%
- Brittle, hard, poor machinability, high tensile strength
- pearlite with cementite at grain boundaries
- high strength and wear resistance in non-cutting tools
Ultra-high (1-2%)
- cutting tools
- High strength and hardness
UCT (Upper critical temperature)
Point at which steel becomes completely austenite.
Martensite:
When rapidly quenched, carbon attempt to go from FCC to BCC but gets trapped, causes internal stresses.
forms BCT structure. Sharp points have a build up of stress
Quench Hardening
Only done to steels above mild grade (enough carbon content to form martensite)
- high brittleness, hard, good wear resistant
Air hardening
Done with steels with some nickel and chromium (<5%) (NiCr)
- heated to red hot and cooled in still air.
Molybdenum usually added to reduce brittleness.
Tempering
Sacrifice some hardness with great increase in toughness
Hardened steel heated to between 200-600, (more temp = more tough)
Needle structure of martensite with some shading of acicular martensite being broken down into ferrite and cementite.
Austempering
Austenitic steal quenches to around 400, held until consistant temp, then queched to room temp
Forms BAINITE: similar to tempered martensite, but more resiliant.
Banite
Formed through austempering
similar to tempered martensite, but more resiliant.
formed when quench rate is not fast enough for martensite
4 Surface hardening techniques and why
Harder outside for scratches, etc, yet tougher inside
Case Hardening (carburisation)
Nitriding
Flame Hardening
Induction hardening
Case Hardening/Carburising
Heating and soaking steel in a carbon rich atmosphere. Increases carbon content on surface, hardness and tensile strength.
- Further heat treatment is difficult, however normalising and hardening of surface possible
Nitriding
Alloy steal heated in furnace with nitrogen present. Performed at 500 for 40-100 hours.
This reacts with alum., chrom, or vanadium.
High hardness, corrosion resistant surface.
Initially costly, and properties lost if heated beyond 500.
Flame Hardening
Applies a flame to localised area then quenched. Mechanised with flame and water jet holder on same assembly
Induction hardening
Similar to flame hardening except using an induction coil. Quenched.
good for camshafts
Austempered Ductile Irons (ADIs)
Austempered spheroidal cast iron/ductile cast iron.
Acicilar ferrite within austenite structure.
Excellent tensile strength, easier to cast, lighter, less affected by sub-zero temperatures, work harden, better damping capacity.
3 ways of changing properties of Steel
- Heat treating
- Alloying
- Carbon content
Manufacturing processes
Forming
Casting
Molding
Joining
Machining
Additive
FCmmJA
For cults, make many acidic juices
Forming: what is, types
Applying forces or pressure to PLASTICALLY deform material
- used for metals, hot or cold working
Forging
Extrusion
Rolling
Casting
Die casting
Sand
Investment
Molding
Used for PLASTICS
injection
Compression
Blow
Joining
Welding
Soldering
Fastening
Machining
Turning
Drilling
Reaming
Additive
3D printing
Laser sintering
Vat photopolymerisation
Hot vs Cold rolling: what, benefits
Hot: above recrystallisation temperature, grains can re-nucleate and grow annealed grains
- easier to plastically deform
- ductile and malleable: unstressed:
- not as dimensionally accurate, bad finish
Cold: below
- increases strength and hardness of material, requires more force to extrude
- more dimensionally accurate, better finish
- more costly (heavier machinery)
BOTH:
- good mechanical properites
- can be fully automated
- high tooling costs
- can’t form complex shapes