Mass Spectrometry Flashcards
What is the purpose of a mass spectrometer
To find the mass of atoms in a sample and to find its abundance
What are the five stages of a mass spectrometer
Vaporisation Ionisation Acceleration Deflection Detection
What happens in the vaporisation part of the mass spectrometer
Atoms are superheated to a gas so they move apart
What happens in the ionisation part of the mass spectrometer
Electrons are fired from the electron gun and remove an electron from the atoms to ionise them
What happens in the acceleration part of the mass spectrometer
Charged plates accelerate the ions so that every atoms has the same kinetic energy
What happens in the deflection part of the mass spectrometer
An electromagnet deflects the samples towards the detector. Because they have the same kinetic energy, the magnitude of deflection depends on their mass. The greater the mass/charge ratio, the less the sample is deflected
What happens in the detection part of the mass spectrometer
Ions are detected as they cause an electrical current in the detector. A spectrum is formed on a computer screen
Describe conditions inside the mass spectrometer
A vacuum as the presence of any other atoms will disrupt the results