m2 - redox Flashcards
oxidation number rules
metals by themselves = 0
oxygen in compounds = -2
hydrogen in compounds = +1
oxidation is…
loss of electrons
increase in oxi number
reduction is
gain of electrons
decrease in oxi number
oxidising and reducing agents
oxidising agents are themselves reduced (accept electrons)
reducing agents are themselves oxidised (donate electrons)
half equation Li to Li+
Cu2+ to Cu
Li -> Li+ + e- (x2)
Cu2+ + 2e- -> Cu (x1)
2Li + Cu2+ -> 2Li+ Cu
how to balance more complex half equations
(MWHE)
balance:
Metal => H2O => H+ => e-
oxygen using Water
hydrogen using H+
charges using Electrons
(also can use oxi states)
when given overall equations, how do you balance them using oxi numbers
work out oxi numbers to see what is oxidised and what is reduced
then make them equal by multiplying
eg if you have +2e- and -4e-, multiply +2e- by 2
iodine thiosulphate titration half equations
I-
S2O3 2-
unknown + I- (excess) —> I2
I2 + thiosuphate (known) —> I-
colours throughout iodine thiosulphate titration
red-brown I2 in conical flask,
adding thio ions will make it go colourless but we need to see exact change
so one it reaches straw yellow we add starch so it will go blue/black
iron and manganate titration colours
purple in burrette, colourless in conical
turns a pale pink once Mn is in excess