M2 - Amount of Substance Flashcards

Amount of substance and the mole, Determination of formulae, Moles and volumes and Reacting quantities

1
Q

How is the molecular formula found?

A

Find empirical formula.
Divide molar mass of a molecule by molar mass of empirical formula.
Multiply empirical formula by the result.

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2
Q

What is the equation for the number of moles of a substance?

A

n=m/Mr
n - number of moles (mol)
m - mass (g)
Mr - molar mass (g/mol)

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3
Q

Define empirical formula (1)

A

Simplest whole number ratio of atoms

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4
Q

What is the percentage yield?

A

The actual yield divided by the theoretical yield expressed as a percentage.

(actual yield / theoretical yield ) X100

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5
Q

What is the concentration of a solute?

A

The amount of solute (in moles) dissolved in each 1dm^3 of solution

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6
Q

What is the value of gas molar volume at room temperature and pressure?

A

1 mole of any gas takes up 24 dm^3/mol at rtp

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7
Q

What is gas molar volume?

A

The volume per mole of a gas.

Measured in dm^3/mol

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8
Q

What are the benefits of a high atom economy?

A

Produce a larger proportion of desired products and few waste products.
Important for sustainability, the best use of natural resources.

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9
Q

How is the empirical formula found?

A
E   Element
M  Mass or %
---  ----------------
M  Molar mass
A   Answer (moles)
     ------------------------
     Smallest answer
R   Ratio
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10
Q

What is atom economy?

A

The molar mass of desired product divided by the sum of the molar masses of all products expressed as a percentage.

(mr of desired products/ mr of total products) X100

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11
Q

What is a titration?

A

A technique used to accurately measure the volume of one solution that reacts exactly with another solution.

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12
Q
A

D

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13
Q

When can a mean titre be worked out?

A

When two or more concordant results are obtained.

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14
Q

What is relative formula mass?

A

The weighted mean mass of the formula unit of a compound compared with 1/12th of an atom of carbon-12

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15
Q

What is stoichiometry?

A

The balancing numbers giving the ratio of the amount, in moles, of each substance in a balanced equation.

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16
Q
A

A

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17
Q

What is the empirical formula?

A

The simplest whole-number ratio of atoms of each element in a compound.

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18
Q

What is the equation to calculate moles of a gas at RTP?

A

n = v / 24

molar gas volume = 24 (dm^3/mol)
n - number of moles (mol)
V - volume (dm^3)

19
Q
A

C

20
Q

What are titrations used for?

A

titrations are used for Finding the concentration of a solution.
Identification of unknown chemicals.
Finding the purity of a substance.

21
Q

What are the standard conditions for temperature and pressure?

A

T = 298K or 25C
P = 1atm or 100kPa

101kPa or 1 atm of pressure

22
Q

What is the limiting reagent?

A

The reactant that is not in excess.

23
Q

What is the molecular formula?

A

The number of atoms of each element in a molecule.

24
Q
A

D

25
Q

What is the equation for finding a solution’s concentration?

A

c=n/v
c - concentration (mol/dm^3)
n - number of moles (mol)
v - volume (dm^3)

26
Q

In hydrated salts, what is the name given to water molecules?

A

Waters of crystallisation

27
Q

Why is the theoretical yield so hard to achieve?

A

The reaction is incomplete.
Competing side reactions giving different products.
Loss of product in handling and purification.
Reversible reaction.

28
Q
A

B

29
Q

What is a mole?

A

The amount of any substance containing as many particles as there are particles in 12g of the carbon-12 isotope.

30
Q

What is relative molecular mass?

A

The mass of a molecule compared with the mass of an atom of carbon-12.

31
Q

Explain what is meant by molecular formula (1)

A

Number and type of atoms making up a molecule

32
Q
A

C

33
Q

What are concordant results?

A

Within 0.10 cm^3 of each other.

34
Q

What are the assumptions made about an ideal gas?

A

Random motion
Elastic collisions
Negligible size
No intermolecular forces

35
Q

What is Avogadro’s Constant?

A

The number of atoms in one mole of the carbon-12 isotope. found in data sheet 6.02X10^23

36
Q

Outline the steps to prepare a 250 cm3 standard solution

A

step 1: find mass of chemical compound you want
step2:
weigh the solid and then
dissolve it, with stirring, in distilled water
pour solution into a 250cm3 volumetric flask
rinse beaker with distilled water into the flask
add distilled water to flask - bottom of meniscus on graduation line
place stopper on flask and invert

37
Q
A

B

38
Q

What is meant by the term mole? (1)

A

Amount of substance that has the same number of particles as there are atoms in 12g of carbon 12

39
Q

What is the ideal gas equation?
State the standard units for each.

A
pV=nRT
p - pressure (Pa)
V - volume (m^3)
n - number of moles (mol)
R - gas constant, 8.314 (J/mol/K)
T - temperature (K)
40
Q

What term is given to the .n H2O part of a formula? (1)

A

Waters of crystallisation

41
Q

What are the balanced equations used to find?

A

The quantities of reactants required to prepare a required quantity of a product.
The quantities of products that should be formed from certain quantities of reactants.

42
Q
A

B

43
Q
A

C