Lipids Flashcards

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1
Q

What are the molecules that make up lipids and what does it lead to them being called?

A

1 glycerol
3 fatty acid
Known as triglycerides

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2
Q

Where do fatty acids join to glycerol?

A

OH groupsu

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3
Q

What is the general formula of glycerol?

A

C3H8O3

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4
Q

What elements do lipids contain?

A

Carbon
Hydrogen
Oxygen

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5
Q

What do fatty acids consist of?

A
  • A carboxyl group COOH.
  • a variable length hydrocarbon chain (CH2)n. There is always an even number of hydrogens between 14 and 22.
  • a methyl group (CH3)
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6
Q

What is the general fatty acid formula?

A

CH3(CH2)nCOOH

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7
Q

Where can saturated fats generally be found?

A

In animals

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8
Q

Where can unsaturated generally be found?

A

Oils in plants

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9
Q

How is a saturated fat’s hydrocarbon chain structured?

A

Single bonds between carbons with all other bonds having hydrogen so it is ‘saturated’ with hydrogen.

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10
Q

What state is a saturated fat at room temperature and why?

A

Solid due to high melting point

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11
Q

What effect does high sat fat intake have?

A

Artheroma (fat) patches developing withing artery lining which can reduce/block blood flow or be taken in blood stream. Contributory factor in heart disease, strokes, etc

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12
Q

How are unsaturated fatty acids’ hydrocarbon chains different from sat?

A

One or more double bond.

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13
Q

What is the difference between mono and polyunsatured?

A

1 carbon-carbon double bond in mono.

2 or more in poly

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14
Q

What effect do the double bonds have?

A

Gives molecules a kink and they tend not to pack together well, giving a more open and therefore oily nature

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15
Q

What is unsaturated’s state at room temp?

A

Liquid

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16
Q

What are the bonds between glycerol and the fatty acids in a triglyceride called and how are they formed?

A

Three ester bonds formed by condensation reactions (releasing 3 water molecules).

17
Q

What are the 2 key properties of Triglycerides?

A

Non-polar so don’t attract water (called hydrophobic molecules).

Insoluble in water (but soluble in some solvents e.g. Acetone and ethanol

18
Q

What is the structural difference of a phospholipid?

A

One fatty acid is replaced by a phosphate group (PO4)3-

on the opposite site of the glycerol.

19
Q

What is the effect of the phosphate group being ionised?

A

It is polar so it attracts water molecules, making the phosphate part of the phospholipid hydrophilic whereas the fatty acid tails are hydrophobic (repel water)

20
Q

What is the phospholipids’ structure important in?

A

Formation of cell membranes

21
Q

What is the test for Lipids/triglycerides?

A

Emulsion Test:-

  • mix the ‘lipid’ with ethanol
  • pour/decant mixture into water
  • white emulsion shows that lipid is present. Stays clear= negative result
22
Q

Use of lipids as an energy store:-

A

Store twice as much as same mass of carbohydrates- very efficient. However, can’t be broken down as quickly to be used in respiration so are only used for medium/long term storage.

23
Q

What the 5 uses of lipids beyond as an energy store?

A
  • thermal insulation
  • protect vital organs like kidneys against physical damage
  • provide buoyancy in aquatic animals
  • provide water-proofing layers. e.g. waxy cuticles on leaves.
  • provide metabolic water source from respiration in organisms in dry environments. E.g. Camels