Lipids Flashcards
Fatty acids in lipids generally has ________ numbers of carbon atoms.
even
Spherical clusters formed by ions
Micelle
Essential Fatty Acids
-Linoleic
-Linolenic
-Arachidonic
An ester of glycerol with three fatty acids
Triglycerides
Triglycerides rich in unsaturated fatty acids are generally _________ and called what?
liquid and oils
Triglycerides rich in saturated fatty acids are generally _________ and called what?
Semisolid/solid and fats
Reduction of some or all of the carbon-carbon double bonds of an unsaturated triglyceride using H2 and transition metal catalyst
Hardening
Breaking of ester bonds by a molecule of water
Hydrolysis
Reverse of esterification
Hydrolysis
Product is glycerol and fatty acid
Acidic condition
Product is glycerol and fatty acid salt
Basic condition
What do you call it when all the fatty acids are removed?
Complete hydrolysis
A fatty acid is left behind in the glycerol
Partial Hydrolysis
Alkaline hydrolysis of a fatty acid ester producing glycerol and 3 fatty acids
Saponification
Test for unsaturation
Halogenation
Oxidation of the double bond of unsaturated fatty acids in lipids resulting to short chain monocarboxylic acid with off-odor
Rancidity
Second most abundant group of naturally occurring lipids
Glycerophospholopids
Also called phosphoglycerides
Glycerophospholipids
The most abundant glycerophospholipids are derived from?
Phosphatidic acid
A molecule in which glycerol is esterified with two molecules of fatty acid and one of phosphoric acid
Phosphatidic acid
Three most abundant fatty acids in phosphatidic acids: (3)
- Palmitic
- Stearic
- Oleic
Hydrolyzed to yield glycerol, fatty acids, phosphate and an amino alcohol
Glycerol Phosphatides
The major lipid components in the myelin sheaths of nerve fiber
Sphingolipids
Hydrolyzed to yield sphingosine, fatty acid, phosphate and an amino alcohol
Sphingomyelins
contain esters formed from long chain carboxylic acids (c16-26) and long chain alcohol (c24-c36)
Waxes
Lipids that does not have an ester bond
Non-saponifiable lipids