Lipids Flashcards

1
Q

Lipids structure

A

chain

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2
Q

Lipids are transported throughout the body for…

A

energy storage

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3
Q

Lipids self-assemble to form…

A

micelles

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4
Q

How do lipids participate in cell signaling?

A

By binding proteins

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5
Q

Fatty acid structure

A

carboxylic acid followed by hydrocarbon chain

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6
Q

Fatty acids usually contain an _____ number of carbons

A

even

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7
Q

Fatty acids become _____ when they’re components of a liquid

A

esterfied

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8
Q

Why are the melting points of unsaturated fatty acids lower than saturated fatty acids?

A

Because unsaturated FAs tend to be in a cis conformation which reduces the molecule’s density

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9
Q

Palmitic acid melting point

A

63.1

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10
Q

Stearic acid MP

A

69.6

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11
Q

Behenic acid MP

A

81.5

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12
Q

Lignoceric acid MP

A

88

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13
Q

Palmitic acid structure

A

CH3(CH2)14COOH

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14
Q

Stearic acid structure

A

CH3(CH2)18COOH

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15
Q

Behenic acid structure

A

CH3(CH2)20COOH

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16
Q

Lignoceric acid structure

A

CH3(CH2)22COOH

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17
Q

Palmitic acid IUPAC

A

Hexadecenoic acid

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18
Q

Stearic acid IUPAC

A

Octadecanoic acid

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19
Q

Behenic acid IUPAC

A

Docosanoic acid

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20
Q

Lignoceric acid IUPAC

A

Tetracosanoic acid

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21
Q

Palmitoleic acid MP

A

-0.5

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22
Q

Oleic acid MP

23
Q

Linoleic acid MP

24
Q

Nervonic acid MP

25
Palmitoleic acid structure
CH3(CH2)5CH=CH(CH2)7COOH
26
Oleic acid structure
CH3(CH2)7CH=CH(CH2)7COOH
27
Linoleic acid structure
CH3(CH2)4CH=CH(CH2)2(CH2)6COOH
28
Nervonic acid structure
CH3(CH2)7CH=CH(CH2)13COOH
29
Palmitoleic acid IUPAC
9-Hexadecanoic acid
30
Oleic acid IUPAC
9-octadecanoic acid
31
Linoleic acid IUPAC
9,12-octadecadienoic acid
32
Nervonic acid IUPAC
15-Tetracosenoic acid
33
What molecule are hormones derived from
cholesterol
34
2 major sources of energy storage
glycogen and triaglycerols
35
What happens after glycogen reserves are used up
full body mobilization of triaglycerols
36
How are triaglycerols stored
in anhydrous form
37
Traiglyceride fatty acids are...
much more chemically reduced compared to monosaccharides
38
What 2 processes do bile salts carry out
1) emulsification of triaglycerides into micelles 2) transport of the micelles across the intestinal lining
39
Glycogen is highly hydrophilic
true
40
Does glycogen or triaglycerides hold more energy?
triaglycerides
41
Bile salts are a derivative of what molecule
cholesterol
42
Pancreatic lipase carries out what reaction
converting triaglycerol into 2-monoacylglycerol using 2H2O and producing 2 free FAs
43
Phospholipase carries out what reaction
converting glycerophospholipid to lysophosphoglyceride using H2O
44
I-FABP
chaperones FAs inside cells to make them soluble and prevent them from disrupting membranes
45
Dietary lipids are repackaged into _____ for distribution
lipoproteins
46
Chylomicrons are ______ synthesized in ______ cells
lipoproteins, intestinal
47
Cholesterol combines with _____ in intestinal cells to form _____ absorbed in chylomicrons
Acetyl CoA, esters
48
Chylomicron pathway
Intestinal cells -> lymph -> peripheral tissues -> liver -> LDL, IDL, VLDL
49
Lipoprotein lipase
clears chylomicron triaglycerides from blood Removes TAG in VLDL
50
What activates lipoprotein lipase
apo C-11, a small apoprotein within chylomicron
51
Reduction pathway of VLDL
VLDL -> IDL -> LDL
52
What does HDL do
transports excess cholesterol back to liver from tissues
53
LDL
enriched in cholesterol and cholesterol esters relative to VLDL and IDL delivery lipoprotein contains very little TAG
54
Atherosclerosis
LDL buildup causing LDL deposition on blood vessel walls