lipids Flashcards
test for lipids
2cm3 sample 5cm3 ethanol
shake thoroughly to dissolve any lipid in the sample
5cm3 water shake gently
milky white emulsion indicates presence
as a control repeat with water instead of sample - remains clear
how do triglycerides form
condensation reaction between 3 fatty acids and 1 glycerol forms ester bonds
contrast saturated and unsaturated fatty acids
saturated - no C=C bonds, straight chain compact
many contact points
higher melting point, solid at room temp
found in animal fats
unsaturated - 1 or more C=C bonds, bends so cannot be tightly packed
few contact points
lower melting point, liquid at room temp
fount in plant oils
relate triglyceride structure to its functions
1) high ratio of high energy storing C-H bonds to C atoms - excellent energy source
2) low mass:energy, much energy stored in small vol - high calorific value from oxidation
3) large, non polar, insoluble, their storage doesn’t have any osmotic effect on cells, insoluble - waterproofing
4) high ratio of H:O atoms, release water when oxidised, provides important source of water for animals
5) slow conductor of heat - thermal insulation
6) less dense than water - buoyancy of aquatic animals
benefit of low mass:energy in triglycerides
much energy can be stored in a small volume, reduces mass animals have to carry around
benefit of high H:O atoms in triglycerides
releases water when oxidised - important water source for animals esp those living in dry climates eg camels store fat in their hump
describe the structure and function of phospholipids
2 fatty acids + phosphate group bonded to glycerol molecule
1) hydrophilic phosphate head
2) hydrophobic fatty acid tail
3) forms phospholipid bilayer in aqueous environment eg at cell surface membranes - waterproof barrier between inside/outside cell
4) hydrophobic tails can splay outside for waterproofing
similarities of triglycerides and phospholipids (4)
1) both have glycerol backbone
2) both may be attached to a mixture of (un)saturated fatty acids
3) both contain C H O atoms
4) both formed by condensation
contrast triglycerides and phospholipids
1) phospholipids have 1 phosphate group instead of a fatty acid
2) p - hydrophilic head and hydrophobic tail. t - hydrophobic
3) p - primarily used in membrane formation. t - storage molecule (oxidation releases energy)
are triglycerides and phospholipids polymers?
no, they are not made of repeating subunits. they are macromolecules