Lipids Flashcards
lipid
hydrophobic compound of C, H, and O
fatty acids
most basic units of triglycerides and phospholipids
consist of C chains 2-80 C in length
basic structure of fatty acids
carboxylic acid group at alpha end
carbon chain
methyl group at omega end
short chain fatty acids
less than 8 carbons long
medium chain fatty acids
8-12 carbons long
long chain fatty acids
12+ carbons long
how does fatty acid chain length affect how we absorb, digest, and metabolize fatty acids?
long chain takes longer to digest/absorb
shorter chains are more H2O soluble
rancidity
when oxidized, foods containing fatty acids may develop bad smell/taste
H is extracted from fatty acid chain, and becomes a free radical (unpaired electron)
free radical makes fatty acid unstable, so O attaches to free electron
unsaturated fats are (more/less) likely to becomes rancid
more; double bonds are less stable
how to decrease rancidity
limit foods exposure to oxygen, heat. and light
hydrogenation
adding H to unsaturated fatty acid to make it more saturated and solid at room temp; aids in stabilization
omega 3 fatty acids
family of PUFA with first double bond between 3rd and 4th carbon from omega end
omega 6 fatty acid
family of PUFA with first double bond between 6th and 7th C from omega end
cis fatty acids
configuration where both H are on same side of double bond
more common in nature
trans fatty acids
configuration where each H are on opposite sides of double bond
found naturally not so often, just in milk and meat
mostly made during hydrogenation
triglyceride
3 fatty acids+glycerol backbone
most common type of lipid found in foods
aka ‘fat’
usually contains mix of fatty acids
phospholipids
2 fatty acids + phosphate group + glycerol backbone
type of lipid
also include a N containing group at head to make head hydrophilic/polar
lecithin
phospholipid made in body
integral to structure of cell membranes
emulsifier
compound that keeps 2 incompatible substances mixed together
sterols
type of lipids that contains 4 connecting rings of C and H
cholesterol is most common
do not contain glycerol or fatty acids
do not provide energy
cholesterol
4 ring sterol and hydrocarbon tail on one end, hydroxyl on other
found only in animal products
kind of sterols most often found in plants
phytosterols and phytostanols
general fat digestion process
lipases remove fatty acids from glycerol backbone by hydrolysis
absorb fat through small intestine and transport by lipoproteins
digestion of fats in mouth
mastication mainly, and warming of solid fats
no digestive enzymes for fats