Lipids Flashcards

1
Q

lipid

A

hydrophobic compound of C, H, and O

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2
Q

fatty acids

A

most basic units of triglycerides and phospholipids

consist of C chains 2-80 C in length

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3
Q

basic structure of fatty acids

A

carboxylic acid group at alpha end
carbon chain
methyl group at omega end

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4
Q

short chain fatty acids

A

less than 8 carbons long

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5
Q

medium chain fatty acids

A

8-12 carbons long

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6
Q

long chain fatty acids

A

12+ carbons long

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7
Q

how does fatty acid chain length affect how we absorb, digest, and metabolize fatty acids?

A

long chain takes longer to digest/absorb

shorter chains are more H2O soluble

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8
Q

rancidity

A

when oxidized, foods containing fatty acids may develop bad smell/taste
H is extracted from fatty acid chain, and becomes a free radical (unpaired electron)
free radical makes fatty acid unstable, so O attaches to free electron

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9
Q

unsaturated fats are (more/less) likely to becomes rancid

A

more; double bonds are less stable

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10
Q

how to decrease rancidity

A

limit foods exposure to oxygen, heat. and light

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11
Q

hydrogenation

A

adding H to unsaturated fatty acid to make it more saturated and solid at room temp; aids in stabilization

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12
Q

omega 3 fatty acids

A

family of PUFA with first double bond between 3rd and 4th carbon from omega end

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13
Q

omega 6 fatty acid

A

family of PUFA with first double bond between 6th and 7th C from omega end

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14
Q

cis fatty acids

A

configuration where both H are on same side of double bond

more common in nature

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15
Q

trans fatty acids

A

configuration where each H are on opposite sides of double bond
found naturally not so often, just in milk and meat
mostly made during hydrogenation

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16
Q

triglyceride

A

3 fatty acids+glycerol backbone
most common type of lipid found in foods
aka ‘fat’
usually contains mix of fatty acids

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17
Q

phospholipids

A

2 fatty acids + phosphate group + glycerol backbone
type of lipid
also include a N containing group at head to make head hydrophilic/polar

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18
Q

lecithin

A

phospholipid made in body

integral to structure of cell membranes

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19
Q

emulsifier

A

compound that keeps 2 incompatible substances mixed together

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20
Q

sterols

A

type of lipids that contains 4 connecting rings of C and H
cholesterol is most common
do not contain glycerol or fatty acids
do not provide energy

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21
Q

cholesterol

A

4 ring sterol and hydrocarbon tail on one end, hydroxyl on other
found only in animal products

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22
Q

kind of sterols most often found in plants

A

phytosterols and phytostanols

23
Q

general fat digestion process

A

lipases remove fatty acids from glycerol backbone by hydrolysis
absorb fat through small intestine and transport by lipoproteins

24
Q

digestion of fats in mouth

A

mastication mainly, and warming of solid fats

no digestive enzymes for fats

25
digestion of lipids in stomach
where digestion really starts | gastric lipase turns triglycerides to diglycerides and free fatty acids
26
small intestine fat digestion
mostly occurs here bile goes into duodenum and emulsifies fat pancreatic lipase hydrolyzes triglycerides phospholipase hydrolyze phospholipids products are then brought into enterocytes via micelles
27
how are glycerol and short/medium chain fatty acids absorbed
absorbed directly into bloodstream through mucosa of small intestine; to portal vein; to liver
28
how are long chain fatty acids and monoglycerides absorbed
they must be reassembled in enterocyte, free long chain fatty acids reattach to monoglycerides and combine with career proteins to form chylomicron
29
chylomicron
type of lipoprotein that carries digestive fat and other lipids through lymph system to blood
30
lipoprotein lipase (LPL)
enzyme that hydrolyzes triglycerides in lipoproteins into 3 fatty acids and glycerol
31
very low density lipoproteins
deliver fat made in liver (triglyceride and cholesterol) to tissues remnants are converted to LDL
32
LDL
deposit cholesterol in artery walls; can lead to heart disease; formed from VLDL
33
HDL
remove cholesterol from tissues and deliiver it to liver to be used as part of bile and/or excreted from body made from cholesterol gathered in tissues and arterial walls
34
components of lipoprotein
lipid center, phospholipid/protein shell
35
essential nutrients that require dietary fat to be absorbed
vitamins A, D, E, K, cholesterol, phospholipids, carotenoids
36
___ of dietary fat needed per day to stimulate formation of chylomicrons
20g
37
linoleic and alpha linolenic acid needed for precursors to form _____
eicosanoids
38
eicosanoids
hormone like structure in body that regulates immune system, blood clotting, inflammation, and BP prostaglandins, thromboxjnes, leukotrines
39
arachidonic acid
omega 6 fatty acid formed from linoleic acid | used to synthesize eicosanoids
40
key role of cholesterol
serve as starting material in synthesis of steroid hormones
41
AMDR for fat
20-35%
42
T/F diet higher in fats but lower in kcal is still good
true
43
saturated fat recommendation per day for heart health
<10%
44
AI for linoleic acid in men; in women
17g/day; 12g/day
45
AMDR for linoleic acid
5-10%
46
AI for alpha linolenic acid in men; in women
1.6g; 1.1g
47
how much essential fatty acids should people with heart disease consume per day
around 1g
48
T/F we should eat as little dietary cholesterol as possible
true
49
trans fats increase ____ and ___ level; decrease ___ level
LDL and triglyceride; HDL
50
carb-based fat substitutes
most fat substitutes | use plant polysaccharides to retain moisture and catlike texture
51
protein-based fat replacements
created from protein in eggs and milk | break down under high temp
52
fat-based fat replacement
modified fats that either mimic fat for lower calories, or block fat absorption mono or diglycerides used as emulsifiers same cal/gram but you use less
53
olestra
fat substitute thats a mix of sucrose and long chain fatty acids
54
most common type of cardiovascular diseaes
coronary heart diseaes