Lipids Flashcards
lipid
hydrophobic compound of C, H, and O
fatty acids
most basic units of triglycerides and phospholipids
consist of C chains 2-80 C in length
basic structure of fatty acids
carboxylic acid group at alpha end
carbon chain
methyl group at omega end
short chain fatty acids
less than 8 carbons long
medium chain fatty acids
8-12 carbons long
long chain fatty acids
12+ carbons long
how does fatty acid chain length affect how we absorb, digest, and metabolize fatty acids?
long chain takes longer to digest/absorb
shorter chains are more H2O soluble
rancidity
when oxidized, foods containing fatty acids may develop bad smell/taste
H is extracted from fatty acid chain, and becomes a free radical (unpaired electron)
free radical makes fatty acid unstable, so O attaches to free electron
unsaturated fats are (more/less) likely to becomes rancid
more; double bonds are less stable
how to decrease rancidity
limit foods exposure to oxygen, heat. and light
hydrogenation
adding H to unsaturated fatty acid to make it more saturated and solid at room temp; aids in stabilization
omega 3 fatty acids
family of PUFA with first double bond between 3rd and 4th carbon from omega end
omega 6 fatty acid
family of PUFA with first double bond between 6th and 7th C from omega end
cis fatty acids
configuration where both H are on same side of double bond
more common in nature
trans fatty acids
configuration where each H are on opposite sides of double bond
found naturally not so often, just in milk and meat
mostly made during hydrogenation
triglyceride
3 fatty acids+glycerol backbone
most common type of lipid found in foods
aka ‘fat’
usually contains mix of fatty acids
phospholipids
2 fatty acids + phosphate group + glycerol backbone
type of lipid
also include a N containing group at head to make head hydrophilic/polar
lecithin
phospholipid made in body
integral to structure of cell membranes
emulsifier
compound that keeps 2 incompatible substances mixed together
sterols
type of lipids that contains 4 connecting rings of C and H
cholesterol is most common
do not contain glycerol or fatty acids
do not provide energy
cholesterol
4 ring sterol and hydrocarbon tail on one end, hydroxyl on other
found only in animal products