Ligand Substitutions Flashcards

1
Q

[Cu(H2O)6]2+ + 4 NH3

A

[Cu(NH3)4(H2O)2]2+ + 4 H2O

solution turns pale blue -> deep blue

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2
Q

[Cu(H2O)6]2+ + 4 Cl-

A

[CuCl4]2- + 6 H2O

solution turns pale blue -> yellow

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3
Q

[Cr(H2O)6]3+ + 3 NH3

A

[Cr(H2O)3(OH)3] + 3 NH4+

solution turns gray-green -> green

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4
Q

Add excess ammonia to the [Cr(H2O)3(OH)3]

A

[Cr(NH3)6]

green precipitate redissolves to form a darker green precipitate

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