Lesson 6- Electronegativity & Polarity Flashcards
Electronegativity
electronegativity is the ability of an individual atom, when bonded, to attract bonding electrons to itself
Ionic bonds are between a metal and a non-metal, and molecular (covalent) bonds are between non-metals, right?
Yes, but there’s a more formal distinction!
However to truly know if it is ionic or covalent we must calculate the difference in the elements’ electronegativities!
ΔEN indicates….
Indicates the degree to which a chemical bond is ionic or covalent!
0 to 0.4 is…
non polar covalent (They are sharing e- equally)
0.41 to 1.69 is…..
polar covalent (unequal sharing)
> 1.7 is…
Ionic (no shakring of elections in a bond)
What do arrows in our drawings represent?
They point towards the more electronegative atom in the bond
Partial charges (δ+ and δ-) are also used to show….
relative charges in a polar covalent bond
Polar Molecules
slightly positively charged at one end and slightly negatively charged at the other because of electronegativity differences
ex. Water
-
Non-Polar Molecules
All molecular elements are non-polar
No dipole moments and partial charges are drawn!
If a molecule has polar BONDS, is the molecule ALWAYS polar?
Not all molecules containing polar covalent bonds are polar molecules!
Shapes and polarity of important molecule: Water–>Bent shape
2 bonding pairs (central atom)
2 lone pairs (central atom)
Polar molecule (if polar covalent bonds)
Bonding pairs
the # of bonds to the atom (count double/triple bonds as ONE bond)
Shapes and polarity of important molecule: Ammonia Molecule–>Trigonal Pyramidal Shape
3 bonding pairs
1 lone pair
Polar molecule
(if polar covalent bonds)
Shapes and polarity of important molecule: Carbon Dioxide Molecule 🡪 Linear Shape
2 bonding pairs
no lone pairs
Non-polar molecule (if polar covalent bonds)