LESSON 2- ENC and Shielding Effect Flashcards
Shielding Electrons
The electrons in the energy levels between the nucleus and the valence electrons
Why are they specifically called shielding
because they “shield” the valence electrons from the force of attraction exerted by the positively charged nucleus.
-This is why valence electrons require less energy to remove than the inner electrons
Example of shielding e with fluorine
In fluorine there are 9 protons in the nucleus and there are 2 shielding electrons in the first energy level between the nucleus and the outer shell
Trend of shielding e within a period
The # of shielding electrons stays the same within a period (except for increasing gradually and erratically across transition metals)
Trend of shielding e with groups
Shielding electrons follow a pattern somewhat like the number of energy levels
They increase in steps as you go down a group
Effective Nuclear Charge (Zeff)
The charge felt by the valence electrons after you have taken into account the number of shielding electrons that surround the nucleus.
How to figure out ENC?
ENC = nuclear charge - # of shielding electrons
ENC (Zeff) = NC - SE
Trend of ENC left to right in a period
The number of protons increase, but the number of shielding electrons stays the same, thus the effective nuclear charge felt by the valence electrons increases
Top-to-bottom in a group with ENC
As you go down a group, the increase in the nuclear charge is cancelled out by the increase in shielding electrons and the effective nuclear charge stays the same