Lectures 1-4 Flashcards

1
Q

The closer the electrons are to the nucleus, do they need more or less energy to leave the atom?

A

More energy they require to leave the atom

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2
Q

What is the first electron shell represent with?

A

1s

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3
Q

What is the second electron shell represented with?

A

2s, 2p

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4
Q

What is the third electron shell represented with?

A

3s, 3p …

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5
Q

What does the number to the power of the letter (s,p…) represent?

A

The number of electrons in that specific shell

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6
Q

Valency is?

A

the atoms ability to enter a combination with other elements. Also the number of electrons that the element gains/loses to get a full outer shell

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7
Q

Electropositive is?

What do they prefer to do?

A

Elements to the left of the period table.

Lose electrons

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8
Q

Electronegative is?

What do they prefer to do?

A

Elements to the right of the period table

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9
Q

Primary bonds

What happens to the electrons?

A

Strong chemical bonds

Shared or transferred

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10
Q

Secondary bonds

What happens to the electrons?

A

Weak interactions between atoms and/or molecules

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11
Q

Examples of primary bonding

A

Ionic, covalent, metallic

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12
Q

Examples of secondary bonding

A

Van der waals, hydrogen bonding

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13
Q

Ionic bonds are formed by…

A

electrons are transferred

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14
Q

Covalent bonds are formed by…

A

electrons being shared

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15
Q

Pros of metallic bonding

A

electrical conductivity, good tensile and compressive strength, high ductility

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16
Q

Van der waals forces, where do these occur?

A

Between atoms or molecules

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17
Q

What is the strength of van der waals forces?

A

Weak

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18
Q

What happens when an induced dipole is formed?

A

As two atoms get close to each other, the negative electrons and the positive nuclei are attracted to eachother, bringing the atoms together with a very small force.

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19
Q

Hydrogen bonding takes place where?

A

Between molecules that have H-F, H-N, and H-O bonds within them

20
Q

In a potential energy and internuclear separation graph, what can we say if the curve is deeper?

A

More potential energy to break the bonds, bond is stronger

21
Q

Coefficient of thermal expansion is?

A

How tolerant a material is towards heat

22
Q

What do systems generally prefer to reach?

A

A minimum energy state or lower enthalpy

23
Q

Crystalline structures are

A

atoms/molecules in a regular repeated form, usually solid

24
Q

Examples of crystalline structures at room temp

A

metals and ceramics

25
Q

Amorphous structures are

A

atoms/molecules in an irregular arrangement

26
Q

Single crystal material is…

A

whole material has a consistent arrangement of atoms

27
Q

Semi-crystalline material is…

A

crystalline regions and amorphous regions

28
Q

Polycrystalline material is…

A

composed of many single crystal regions or grains that are oriented at random

29
Q

Polymorphic materials can adopt more than one what?

A

More than one crystal structure

30
Q

Allotropic structures are…

A

pure elements that can adopt different crysal structure depending on the different temperatures and pressures

31
Q

Examples of crystal structures

A

NaCl sodium chloride, graphite and diamond

32
Q

What does face centred cubic mean?

A

Circle faces showing on each side of the cube

33
Q

What does body centred cubic mean?

A

The central sphere is contained in the centre of the cube

34
Q

What does a hexagonal close packed structure look like?

A

Two hexagons forming a prism, with three additional atoms at equidistance from every atom forming a triangle

35
Q

Vacancy in a material is

A

hole in the crystal of a material, absence of an atom

36
Q

Dislocation in a material is

A

defects when half a row of atoms are missing from the crystalline layer and the surrounding layers of the crystal close in.

37
Q

What is the pro to vacancy

A

Enable relative easy diffusion of atoms through a solid lattice

38
Q

Yield stress is

A

the maximum amount of force a material can take before it is inelastically deformed

39
Q

Tensile load is

A

force putting a material under tension

40
Q

Shear stress is

A

forces being applied which slide the layers in a crystal along side eachother

41
Q

Plastic deformation is when

A

the material becomes permanently deformed

42
Q

Edge dislocation slip is when

A

a shear stress is applied to a structure with a dislocation and then the atoms below the dislocation break their bonds and slide along. Until the dislocation is then at one end of the crystal structure.

43
Q

Dislocations in a material allow it to be

A

ductile

44
Q

The presence of dislocations in a material allow the planes of atoms to…

A

slip past eachother at lower applied stresses

45
Q

Ionic and covalent bonds are more what compared to metals

A

Brittle/less ductile

46
Q

Slip is usually easier in the direction of the atoms where they are…

A

more closely packed