Lecture 4 Flashcards
What is ATP?
- cellular source of energy
- supplied by macronutrients in the diet
- sustains physical energy, metabolism, active transport, etc.
What is a Calorie?
measure of heat to express the energy content of food
What is the conversion of a chemistry calorie vs a food calorie?
1000 chemistry calries = 1 food Calorie
What is the difference between calorie and Calorie?
calorie = chemistry
Calorie = food
What is the conversion of food Calorie to kcal to KJ?
1 food Calorie = 1 kcal = 4.18 KJ
What is the method used to estimate energy in foods?
Calorimetry = measurement of heat production
What is calorimetry?
Uses heat as an indicator of the amount fo energy stored in the chemical bonds of foods (carbon-hydrogen bonds), when these bonds are broken down, they release heat
What is bomb calorimetry?
works according to the principles of direct calorimetry (directly measures the amount of energy stored in chemical bonds of foods)
What are the steps to bomb calorimetry?
- dry and weigh sample (1g) and place in enclosed chamber (the bomb) with oxygen
- The sample is ignited
- heat that is released is absorbed by water and measured
What is the heat of combustion equal to?
Heat of combustion (gross energy) = maximum energy during a chemical reaction
What are the potential errors of bomb calorimetry?
- overestimates energy (we don’t digest food like a bomb calorimeter burns it)
- doesn’t take into account the energy needed for digestion and absorption
What are the physiological fuel values? (Atwater values)
CHO = 4
Fat = 9
Protein = 4
What is the formula for the physiological fuel values?
[Heat of combustion(gross energy) - energy lost in urine] x apparent digestibility
(a-b) x c
What are the units of the factors in the formula for physiological fuel values?
Heat of combustion(gross energy) = kcal/g
Energy lost in urine = kcal/g
Apparent digestibility = %
What are two other names for physiological fuel values?
available energy
metabolizable energy
Why does fat provide more kcal/g vs CHO or protein?
The heat of combustion (kcal/g) describes the total energy released during a chemical reaction between a hydrocarbon and oxygen to release CO2 and H2O and heat. The chemical structure of CHO, fat and protein influences the heat of combustion for macronutrients
CHO - ratio of hydrogen to oxygen = 2:1
Protein - has nitrogen which affects gross energy measurement, however in the body, nitrogen combines with hydrogen and is eliminated as urea. This loss of hydrogen affects the heat of combustion
Lipid - lipids are less oxidized than CHO and protein, ratio of hydrogen to oxygen is much greater than 2:1, lipids have lots of hydrogen atoms available for cleavage oxidation for energy