Lecture 28 Flashcards

1
Q

What happens to KE when temperature increases

A

The KE increases, particles move faster and overcome attractions more easily

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2
Q

What happens to KE when temperature decreases

A

KE decreases, particles move slowly and attractions can pull them together more easily

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3
Q

What is the process of solid -> gas called

A

Sublimation

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4
Q

What is the process of gas -> solid called

A

Deposition

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5
Q

What is the process of liquid -> gas called

A

Vaporization

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6
Q

What is the process of gas -> liquid called

A

Condensation

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7
Q

What changes are exothermic (release heat)

A

Condensation
Freezing
Deposition

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8
Q

What processes are endothermic (absorb heat)

A

Sublimation
Melting
Vaporization

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9
Q

What is distrupted during a phase change

A

Non-bonding forces

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10
Q

Why is Hfus < Hvap

A

It takes less energy to reduce intermolecular forces enough to move particles out of their fixed positions than to separate them completely

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11
Q

What happens when frost forms

A

Deposition, exothermic

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12
Q

What happens in the equilibrium process

A

The rate of vaporization and condensation are equal

Same number of molecules entering & leaving the liquid (pressure remains constant)

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13
Q

Why is equilibrium dynamic

A

Because there is still movement in the molecules

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14
Q

What effect does temperature have on vapour pressure

A

It changes the fraction of molecules moving fast enough to escape into the the gas phase and the ones not moving fast enough to recondense into a liquid

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15
Q

What happens when the rate of vaporization matches the rate of condensation

A

A dynamic equilibrium is (1=g) is established, as long as there is liquid present the pressure reaches a constant value called vapour pressure

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16
Q

The higher the temperature the ————- the vapour pressure

A

Higher

17
Q

What is the vapour pressure of strong/weak intermolecular forces

A

Strong IMF: low vapour pressure (ex. H2O)

Weak IMF: high vapour pressure (ex. Diethyl ether)

18
Q

What is the normal boiling point

A

The temperature at which the vapour pressure is 1 atm

19
Q

Define boiling point

A

Temperature at which the vapour pressure in the liquid equals the external pressure, which is usually the atmospheric pressure

20
Q

Explain volatile substances

A
  • high vapour pressure
  • low bp
  • weak IMF
21
Q

Explain non-volatile substances

A
  • low vapour pressure
  • high bp
  • strong IMF