Lecture 2-The structure of an atom Flashcards

1
Q

Z

A

Atomic number

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2
Q

A

A

Mass number

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3
Q

What are orbitals?

A

When e- occupy specific regions in space

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4
Q

What is it called when orbitals are grouped into families?

A

Shells

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5
Q

How do e- determine the properties of an atom?

A

By affecting reactivity + ability to form bonds

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6
Q

What is the kinetic isotope effect?

A

Where heavier isotopes react slightly more slowly , because of the strength of the bonds

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7
Q

Stable isotopes remain ……..?

A

Unchanged indefinitely

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8
Q

What do unstable isotopes undergo to obtain a stable nucleus?

A

spontaneous disintegration

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9
Q

What does spontaneous integration result in?

A

The emission of small particles and / or radiation

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10
Q

What do radioactive isotopes have?

A

High energy nucleus

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11
Q

What does a mass spectrometer do?

A

Measure the molecular weight of atoms/compounds by observing the m/z of ratios

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12
Q

What does half-life t1/2 mean?

A

The time taken for the activity of a given amount of a radioactive substance to decay to half of its initial value

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13
Q

What emits during alpha decay?

A

Helium nuclei

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14
Q

What emits during beta minus decay?

A

electron

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15
Q

What emits during beta plus decay?

A

positron (same mass of e-, but different charge)

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16
Q

What emits during gamma rays?

A
  • gamma photons

- high energy EM radiation

17
Q

What is capture process?

A

When a small particle (e-/neutron) collides + combines with a nucleus

18
Q

PENETRATING POWER
Alpha
Beta
Gamma

A

Paper
Aluminium
Lead

19
Q

Industrial applications of radioactive isotopes?

A
  • Energy generation
  • Sterilization of food + medical supplies (60Co)
  • Imaging + gauging
20
Q

Domestic applications of radioactive isotopes?

A

Smoke detectors using 241Am-alpha source

21
Q

Medical applications of radioactive isotopes?

A
  • Diagnostic

- Therapeutic

22
Q

Why should a radioisotope used in diagnosis emit gamma rays of sufficient energy?

A

So it can escape the body + have a half-life short enough for it to decay away soon

  • 99Tcm commonly used
  • emits gamma + low energy beta particles
23
Q

What isotopes are involved in myocardial perfusion imaging ?

A

201TICL
82Rb
99Tcm
-detection + prognosis of coronary artery disease

24
Q

What isotope is involved in PET imaging?

A

18F-Fluoro-deoxy glucose

-measure cell metabolism

25
Q

What are 18F-compounds used for?

A

Imaging DNA synthesis + hypoxia

26
Q

What are the requirements for radioisotopes for therapy?

A

A strong beta emitter—->damage cells in a small area

-Can be implanted near a tumour / injected

27
Q

What is radioiodine used for?

A

Diagnostics, overactive thyroid

28
Q

What is 89SrCL used for?

A

Bone metastasis