Lecture 13-16 Flashcards
The greenhouse effect
Retention of solar energy in the form of heat
The result of GHG
Greenhous gas GHG
Atmospheric gas which can absorb infrared radiation
Major elemental composition of Earth’s atmosphere
Methane, carbon dioxide, water vapour
What type of light energy is involved in greenhouse effect
Shortwave radiation: visible light, has very short wavelength
- comes from the sun (some of this energy is absorbed and then reflected by the Earth
- process changes wavelengths from shorter visible light to longer infrared radiation
Infrared radiation: has longer wavelengths
What kind of movements do two-atom gas molecules make?
Stretching
example: oxygen, nitrogen
What kind of movements do >2 atom molecules make?
Stretching and bending
Why does solar radiation pass through atmospheric gasses without interacting?
Neither bending or stretching vibrations fall within the same wavelength range as visible light
How do molecules interact with infrared radiation?
Bending vibrations are slower than strethcing vibrations
For some molecules, the rate of movement for bending vibrations can fall within the wavelength range of infrared radiation, hence interacting with infrared radiation.
How do GHG absorb and radiate heat?
Infrared radiation interaction causes bending vibrations to move more vigorously
Some energy from infrared radiation is captured and then radiated outward
- Some to space, where it is lost
- Some back to the planet –> heat
Examples of GHG
Water vapour
Carbon dioxide
Methane
Nitrous oxide
Chlorofluorocarbons (CFCs)
ozone
Who utilizes photosynthesis?
Autotrophs who acquire energy from sunlight
Who utilizes cellular respiration?
Heterotrophs to derive energy from sugars
Autotrophs to use sugar energy fixed through photosynthesis
All large multicellular life requires aerobic cellular respiration in order to produce enough energy to support metabolism and growth (oxygen as an electron donor to produce energy)
How can species thrive in niches without the presence of oxygen and/or carbon?
Some forms of life can produce energy using different electron donors and acceptors
These alternative reactions produce less ATP than aerobic cellular respiration
Generally these types of energy acquisition are believed to have evolved before photosynthesis
- persist in environments devoid of sunlight and/or oxygen.
Chemoautotrophs
Life that uses inorganic substances as electron donors or acceptors other (exclude either carbon, oxygen or both)
Although chemoautotrophs are single-celled organisms, their impact on the global cycle of elements is significant
- Bacteria are the main driver of the global nitrogen cycle
What are some reactions where molecules other than carbon are the electron donor (O2 is the electron acceptor)
Nitrification (nitrifying bacteria, e.g. in well-aerated soils)
Sulphur oxidation (sulphur-oxidizing bacteria)
Iron reduction
Methanogenesis
How do species near deep sea hydrothermal vents get their energy?
Far from sunlight –> primary producers can’t use photosynthesis
Food chains for some persist mainly from the energy produced by sulfur oxidizing bacteria
How do cows produce GHG
Enteric fermentation –> burps out methane
How do we compare GHG?
Two main metrics to compare the relative impact of a gas on the greenhouse effect:
1) Residence time (also called atmospheric time)
2) Global Warming Potential GWP (also called relative radiative forcing)
Residence time in relation to GHG
The amount of time a greenhouse gas remains in the atmosphere reservoir
Global warming potential (GWP)
Measure the contribuation of a gas on global warming, using CO2 as a standard
For a given time period: how much infrared energy 1 ton of gas will absorb, compared to 1 ton of CO2 (often measured out of 100 years)
Why do we say that time period used to measure GWP can be deceiving depending on the residence time?
Divided over a longer time period, GWP seems smaller
Example methane:
- 25 to 28 GWP over 100 years
But residence time is only 10-12 years
Methane does most of its damage quickly then leaves
If measured on a 20 year time scale, GWP of methane=80.
What are the most impactful gases based on GWP, residence time, current atmospheric concentration and human influence?
Carbon dioxide: GHG with the higher concentration in the atmosphere presently
Methane: traps 25x more heat than CO2. Has the greatest future potential to impact global temperatures.
Nitrous oxide: has high GWP and residence time, and is released as a part of agriculture. Difficult to stop.
What are the natural sources of methane?
Methanogens
- Bacterial species (found in areas lacking oxygen)
- Animals which ferment their food during digestion
What are some anthropogenic sources of methane?
Agriculture: animal husbandry (cows) and crops (rice in particular)
Energy: natural gas is mainly methane, processing of petroleum releases methane
Is atmospheric CH4 mainly antropogenic or natural?
60% anthropogenic
Rates of methane release have increased twice as fast as CO2 in the 20th century
Does methane have a cycle?
Since methane is produce through biological processes it fluctuates seasonally similarly to CO2
When bacteria freezes, there is a drastic production in methane –> seasonal fluctuations
Depending on location, there is variation (how near to the equator –> less fluctuation)
Methane leaves the atmosphere mainly through reactions with OH- ions in the atmosphere
- Through a long series of reactions –> converts CH4 to CO2
How does the cattle industry participate in methane production?
Major source
Methanogenesis takes place during the digestion of foods in ruminant mammals
High biomass of cows globally results in high impact
Permafrost
Soil water which has remained frozen for a minimum of 2 continuous years
Decomposition in the absence of O2 –> methanogenesis (whereas in the presence of O2 –> respiration)
Every season, when a bit of the top layer defrosts, plants and soil microbes spring to life. Some of the permafrost melts
During the warm period, organic matter can build up (does not have the time to decompose fully)
Decomposing matter builds up over time
Complete melting of deep permafrost
- Rapid decomposition of stored organic matter (in absence of O2 in the soil –> produce methane and carbon dioxide)
What kind of feedback does melting permafrost engender with increasing atmospheric temperature?
Positive feedback between melting permaforst and increasing atmospheric temperature
Melting permafrost –> atmospheric GHG –> increasing temperatures
Estimated 1500 Gt methane and CO2 held in permafrost globally
Tipping point: we will not be able to stop the melting on permafrost
Natural nitrous oxide
Natural part of the nitrogen cycle
- produced by bacteria in the soil
- Lightning breaking N3 bonds in the atmosphere
Anthropogenic contributions nitrous oxide
Produced as a byproduct of agriculture
- Nitrogen fertilizer used for crops feed bacteria, which produce more nitrous oxide
Less contributor to GHG, but increasing
How is nitrous oxide removed from the atmosphere?
Removed by bacteria
breakdown by UV radiation
How to calculate residence time for excess CO2
R.T. (yrs)= excess C (GtC)/Net C(sink) (GtC/year)
This assumes a well mixed reservoir with a simple removal process
Why does taking out excess CO2 from the atmosphere happen very slowly?
Because of the multiple layers of different sinks and linkages involved in taking out CO2 from the atmosphere
What is the relative impact of a specific gas on the greenhouse effect a result of?
- The atmospheric concentration
- The relative ability to absorb infrared radiation
- The estimated residence time of a molecule in the atmosphere
Climate trends definition
global temperature change over a set period of time (generally over long geological time periods)
Climate rhythms definition
Repeating cycles of climate (generally shorter on a geological timescale)
What is Earth’s climate defined by?
Global temperature averages (not weather patterns)
Climate vaires between hot and cold global averages
Climate rhythms in recent history
Rapidly repeating rhythms of mild temperature changes
Ice Age
Persistent glaciers present
Glacial period
Glaciers are growing
Interglacial period
Glaciers are receding
Currently in a warm interglacial period that began approx.11 000 years ago